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The reaction of dilithium phthalocyanine with tris(2,2,6,6-tetramethylheptane-3,5-dionato) Lnlll (Ln = Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Y) affords a series of (p-phthalocyaninato) (diketonato),Ln, complexes; the X-ray crystal structure of the samarium compound shows that the phthalocyanine ligand bridges two samarium atoms each co-ordinated by two /3-diketonato ligands, and important molecular parameters include Sm-Oav 2.284(17), Sm-Nav 2.656(16), and Sm-Smav 3.627(3) A.
Preparation and x-ray crystal structure (for Ln = Sm) of (μ-phthalocyaninato)bis[di(2,2,6,6-tetramethylheptane-3,5-dionato)Ln III] (Ln = Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Y)
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