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Anion-Selective Electrodes Based on Porphyrin Complexes of Tetravalent Metal Ions
https://nitech.repo.nii.ac.jp/records/3536
https://nitech.repo.nii.ac.jp/records/35368e1e33f0-1734-4a76-aaab-6825f26b259e
名前 / ファイル | ライセンス | アクション |
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本文_fulltext (230.2 kB)
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2001 c The Japan Society for Analytical Chemistry
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2012-11-06 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Anion-Selective Electrodes Based on Porphyrin Complexes of Tetravalent Metal Ions | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Hattori, Hiroyuki
× Hattori, Hiroyuki× Komiya, Shigeki× Yuchi, Akio |
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著者別名 | ||||||
姓名 | 湯地, 昭夫 | |||||
書誌情報 |
Proceedings of IUPAC International Congress on Analytical Sciences 2001 (ICAS 2001) p. i1353-i1356, 発行日 2001 |
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出版者 | ||||||
出版者 | The Japan Society for Analytical Chemistry | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
内容記述 | ||||||
内容記述タイプ | Other | |||||
内容記述 | The performance of tetravalent metal complexes with tetraphenylporphine (H2tpp) as ionophores for ion-selective electrodes was studied. In the case of [MO(tpp)] (M: Ti, V), protonation to the oxo group is responsible for pH response, and anionic response following a Hofmeister series is ascribed to their coextraction as counter anions. In the case of [M(tpp)Cl2] (M: Zr, Hf), replacement of chloride with anions including OH- is responsible for pH and anionic responses, and Lewis acid-base interactions produce preferential response to F-, NO2 -, and acetate. The [Zr(tpp)Cl2]-based electrode was successfully used for potentiometry of acetic acid in rice vinegar. | |||||
フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf |