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陰イオン選択性電極感応膜中における複核ジアルキルスズ(IV)錯体の生成によるα-ヒドロキシカルボン酸選択性
https://nitech.repo.nii.ac.jp/records/3586
https://nitech.repo.nii.ac.jp/records/3586486c32aa-57e8-4987-8493-a0d9fc170a2f
名前 / ファイル | ライセンス | アクション |
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本文_fulltext (780.8 kB)
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c 2008 The Japan Society for Analytical Chemistry
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2012-11-06 | |||||
タイトル | ||||||
タイトル | 陰イオン選択性電極感応膜中における複核ジアルキルスズ(IV)錯体の生成によるα-ヒドロキシカルボン酸選択性 | |||||
言語 | ||||||
言語 | jpn | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
その他(別言語等)のタイトル | ||||||
その他のタイトル | α-Hydroxycarboxylate Selectivity by Spontaneous Formation of Dimeric Dialkyltin (IV) Complexes in Membrane of Anion-Selective Electrode | |||||
著者 |
鈴木, 崇嗣
× 鈴木, 崇嗣× 可児, 真平× 湯地, 昭夫 |
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著者別名 | ||||||
姓名 | Yuchi, Akio | |||||
書誌情報 |
分析化学 = Japan analyst 巻 57, 号 8, p. 683-686, 発行日 2008 |
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出版者 | ||||||
出版者 | 日本分析化学会 | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 05251931 | |||||
書誌レコードID(NCID) | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AN00222633 | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
DOI | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | DOI | |||||
関連識別子 | http://dx.doi.org/10.2116/bunsekikagaku.57.683 | |||||
関連名称 | 10.2116/bunsekikagaku.57.683 | |||||
内容記述 | ||||||
内容記述タイプ | Other | |||||
内容記述 | The liquid-membrane ion-selective electrode based on bis(pentafluorobenzyl)tin(IV) dibromide showed higher selectivities to α-hydroxycarboxylates than to other carboxylates without any hydroxyl group and those with a β-hydroxy group. The calibration curve for citrate was linear over a range of 10-4 to 10-2 mol dm-3 with a potential slope of -60 mV/decade. The equilibrium study on the complexation between dimethyltin(IV) and a series of carboxylates indicates the formation of stable, neutral and dimeric complexes only with α-hydroxycarboxylates, [(Me2Sn)2(H-1hc)2] {(H-1hc)-2 : species formed by deprotonation of α-hydroxycarboxylates (hc-) at α-OH groups}. The corresponding species may be spontaneously formed as electroactive species in the liquid membrane containing bis(pentafluorobenzyl)tin(IV) dibromide and acquire the selectivity to α-hydroxycarboxylates. | |||||
フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf |