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Transition-metal-catalysed Grignard reaction of secondary allylic phosphates
https://nitech.repo.nii.ac.jp/records/3783
https://nitech.repo.nii.ac.jp/records/3783eb4cf90c-b7c2-47b5-aa74-3bb55c58a977
名前 / ファイル | ライセンス | アクション |
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本文_fulltext (606.1 kB)
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J. CHEM. SOC. PERKIN TRANS. I 1984, 969-972 - Reproduced by permission of The Royal Society of Chemistry (RSC)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2012-11-06 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Transition-metal-catalysed Grignard reaction of secondary allylic phosphates | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Araki, Shuki
× Araki, Shuki× Butsugan, Yasuo |
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著者別名 | ||||||
姓名 | 荒木, 修喜 | |||||
書誌情報 |
Journal of the Chemical Society. Perkin transactions 1 巻 1984, p. 969-972, 発行日 1984-01-01 |
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出版者 | ||||||
出版者 | Royal Society of Chemistry | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0300922X | |||||
書誌レコードID(NCID) | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA00695134 | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
DOI | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | DOI | |||||
関連識別子 | http://dx.doi.org/10.1039/P19840000969 | |||||
関連名称 | 10.1039/P19840000969 | |||||
内容記述 | ||||||
内容記述タイプ | Other | |||||
内容記述 | Regio- and stereo-chemistry of transition-metal-catalysed Grignard reactions of secondary allylic phosphates have been investigated. Best results for regioselective carbon-carbon bond formation at the γ-position of secondary allylic phosphates were attained when copper(I) iodide was used as the catalyst. The naturally occurring monoterpene alcohols, geraniol and the sex pheromone of the African Monarch, were synthesized as a demonstration of the synthetic utility of the newly developed coupling reaction. | |||||
フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf |