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Raman spectra of potassium trans-4-hexenoate and conformational change on micellization
https://nitech.repo.nii.ac.jp/records/3920
https://nitech.repo.nii.ac.jp/records/39203f648a3a-a65c-4d6a-b9da-baeb00652b34
| 名前 / ファイル | ライセンス | アクション |
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本文_fulltext (899.5 kB)
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J. Chem. SOC., Faraday Trans. I , 1988, 84(5), 1639-1651-Reproduced by permission of The Royal Society of Chemistry (RSC)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||||||||||||||||||
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| 公開日 | 2012-11-06 | |||||||||||||||||||||
| タイトル | ||||||||||||||||||||||
| タイトル | Raman spectra of potassium trans-4-hexenoate and conformational change on micellization | |||||||||||||||||||||
| 言語 | en | |||||||||||||||||||||
| 言語 | ||||||||||||||||||||||
| 言語 | eng | |||||||||||||||||||||
| 資源タイプ | ||||||||||||||||||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||||||||||||||
| 資源タイプ | journal article | |||||||||||||||||||||
| 著者 |
Okabayashi, Hirofumi
× Okabayashi, Hirofumi
× Tsukamoto, Koji
× Oshima, Kunihiro
× 多賀, 圭次郎
× Nishio, Etsuo
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| 著者別名 | ||||||||||||||||||||||
| 姓名 | Taga, Keijiro | |||||||||||||||||||||
| 言語 | en | |||||||||||||||||||||
| 姓名 | 多賀, 圭次郎 | |||||||||||||||||||||
| 言語 | ja | |||||||||||||||||||||
| 姓名 | タガ, ケイジロウ | |||||||||||||||||||||
| 言語 | ja-Kana | |||||||||||||||||||||
| bibliographic_information |
en : Journal of the Chemical Society. Faraday transactions 1. 巻 84, 号 5, p. 1639-1651, 発行日 1988-01-01 |
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| 出版者 | ||||||||||||||||||||||
| 出版者 | Royal Society of Chemistry | |||||||||||||||||||||
| 言語 | en | |||||||||||||||||||||
| ISSN | ||||||||||||||||||||||
| 収録物識別子タイプ | ISSN | |||||||||||||||||||||
| 収録物識別子 | 0300-9599 | |||||||||||||||||||||
| item_10001_source_id_32 | ||||||||||||||||||||||
| 収録物識別子タイプ | NCID | |||||||||||||||||||||
| 収録物識別子 | AA00695112 | |||||||||||||||||||||
| 出版タイプ | ||||||||||||||||||||||
| 出版タイプ | VoR | |||||||||||||||||||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||||||||||||||||||
| item_10001_relation_34 | ||||||||||||||||||||||
| 関連タイプ | isIdenticalTo | |||||||||||||||||||||
| 識別子タイプ | DOI | |||||||||||||||||||||
| 関連識別子 | http://dx.doi.org/10.1039/F19888401639 | |||||||||||||||||||||
| 関連名称 | 10.1039/F19888401639 | |||||||||||||||||||||
| 内容記述 | ||||||||||||||||||||||
| 内容記述タイプ | Other | |||||||||||||||||||||
| 内容記述 | The infrared and Raman spectra of potassium trans-4-hexenoate (PT4H) have been measured in the crystalline state and in aqueous solution. Normal coordinate calculations have been carried out to explain the vibrational spectra. For crystalline PT4H it is concluded from the vibrational spectra in the 700-100 cm-1 region that the trans-skew (TS) and trans-cis (TC) forms coexist at 300 K and the TS form is stabilized at 100 K. For the PT4H ions in aqueous solution the TS form was found to be predominantly stabilized on micellization. In particular, the Raman spectra of a PT4H-H2O solution in the 1700-700 cm-1 range were investigated at various concentrations, and it was found that the stabilization of the TS form is reflected in vibrational modes characteristic of the -CH=CH- and CH2 groups. The difference Fourier-transform infrared (F.t.i.r.) spectra of PT4H-H2O (or PT4H-D2O) solutions have also been measured at various concentrations. The infrared absorption spectra of water were successfully cancelled out in the 1500-900 cm-1 region for H2O and in the 1700-1300 and 1000-700 cm-1 regions for D2O. The concentration dependence of the difference F.t.i.r. spectrum was used to investigate conformational changes upon micellization. | |||||||||||||||||||||
| 言語 | en | |||||||||||||||||||||
