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Pressure dependence of the polarized reflectance spectrum of the solid charge-transfer complex, perylene-TCNQ: Estimation of microscopic parameters
https://nitech.repo.nii.ac.jp/records/4008
https://nitech.repo.nii.ac.jp/records/4008fa4da5a3-c6ae-48b2-93be-78ecf9771af9
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
本文_fulltext (453.7 kB)
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Copyright (1989) American Institute of Physics. This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Institute of Physics.The following article appeared in Journal of Chemical Physics, 91(6), pp.3450- 3455 ; 1989 and may be found at http://link.aip.org/link/?jcp/91/3450
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||||||||||||||
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| 公開日 | 2012-11-06 | |||||||||||||||||
| タイトル | ||||||||||||||||||
| タイトル | Pressure dependence of the polarized reflectance spectrum of the solid charge-transfer complex, perylene-TCNQ: Estimation of microscopic parameters | |||||||||||||||||
| 言語 | en | |||||||||||||||||
| 言語 | ||||||||||||||||||
| 言語 | eng | |||||||||||||||||
| 資源タイプ | ||||||||||||||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||||||||||
| 資源タイプ | journal article | |||||||||||||||||
| 著者 |
井田, 隆
× 井田, 隆
× Yakushi, Kyuya
× Kuroda, Haruo
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| 著者別名 | ||||||||||||||||||
| 姓名 | 井田, 隆 | |||||||||||||||||
| 言語 | ja | |||||||||||||||||
| 姓名 | イダ, タカシ | |||||||||||||||||
| 言語 | ja-Kana | |||||||||||||||||
| 姓名 | Ida, Takashi | |||||||||||||||||
| 言語 | en | |||||||||||||||||
| 書誌情報 |
en : Journal of Chemical Physics 巻 91, 号 6, p. 3450-3455, 発行日 1989-09-15 |
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| 出版者 | ||||||||||||||||||
| 出版者 | American Institute of Physics | |||||||||||||||||
| 言語 | en | |||||||||||||||||
| ISSN | ||||||||||||||||||
| 収録物識別子タイプ | ISSN | |||||||||||||||||
| 収録物識別子 | 0021-9606 | |||||||||||||||||
| item_10001_source_id_32 | ||||||||||||||||||
| 収録物識別子タイプ | NCID | |||||||||||||||||
| 収録物識別子 | AA00694991 | |||||||||||||||||
| 出版タイプ | ||||||||||||||||||
| 出版タイプ | VoR | |||||||||||||||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||||||||||||||
| 内容記述 | ||||||||||||||||||
| 内容記述タイプ | Other | |||||||||||||||||
| 内容記述 | The polarized reflectance spectrum of the perylene TCNQ complex has been measured at high pressure up to 27 kbar using a diamond anvil cell incorporated into a microspectrophotometer. The degree of charge transfer (ρ), the transfer integral (t), and the site‐energy difference (Δ) are estimated at each pressure from analysis of the charge‐transfer band. The pressure dependences of t and Δ are found to be ∂ ln t/∂P=+2.3% kbar 1 and ∂Δ/∂P= 6.4 MeV kbar 1, respectively. It is shown that the observed pressure dependence of the stabilization energy of the charge‐transfer excited state is mainly attributable to the change in the electrostatic energy accompanying the lattice contraction. | |||||||||||||||||
| 言語 | en | |||||||||||||||||
