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Semi-xylenol orange complex of zirconium(IV) as a photometric reagent system for fluoride based on mixed ligand complex formation
https://nitech.repo.nii.ac.jp/records/4188
https://nitech.repo.nii.ac.jp/records/418854d37d85-4b0d-426d-bb78-5deea971bdf0
名前 / ファイル | ライセンス | アクション |
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本文_fulltext (529.0 kB)
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Analyst, February 1993, Vol. 118, 219-222 -Reproduced by permission of The Royal Society of Chemistry (RSC)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2012-11-06 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Semi-xylenol orange complex of zirconium(IV) as a photometric reagent system for fluoride based on mixed ligand complex formation | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Yuchi, Akio
× Yuchi, Akio× Hokari, Norihisa× Wada, Hiroko× Nakagawa, Genkichi |
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著者別名 | ||||||
姓名 | 湯地, 昭夫 | |||||
書誌情報 |
Analyst 巻 118, 号 2, p. 219-222, 発行日 1993-01-01 |
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出版者 | ||||||
出版者 | Royal Society of Chemistry | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 00032654 | |||||
書誌レコードID(NCID) | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA00524823 | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
DOI | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | DOI | |||||
関連識別子 | http://dx.doi.org/10.1039/AN9931800219 | |||||
関連名称 | 10.1039/AN9931800219 | |||||
内容記述 | ||||||
内容記述タイプ | Other | |||||
内容記述 | An equimolar mixture of zirconium(IV) and Semi-Xylenol Orange (SXO) reacts rapidly with fluoride ion at pH 2 to cause an increase in absorbance at about 530 nm. The calibration graph was linear up to 1×10-5 mol dm-3. In a flow injection system, a detection limit (signal-to-noise ratio=3) of 2.5×10-7 mol dm-3 was obtained with a sample throughput of 60 h-1. Potentiometric studies of this reaction system with a fluoride ion-selective electrode demonstrated that an increase in absorbance can be ascribed to the coordination of the phenolic oxygen of SXO on the reaction of a partly hydrolysed Zr-SXO complex with fluoride ion to give the mixed ligand complex. | |||||
フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf |