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Preparation and metal ion-binding properties of gramicidin S derivatives carrying picolinoyl groups on the ornithine side chains
https://nitech.repo.nii.ac.jp/records/4538
https://nitech.repo.nii.ac.jp/records/4538e279942a-8a01-45ec-86f2-bbf6ef56e313
名前 / ファイル | ライセンス | アクション |
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本文_fulltext (203.4 kB)
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J. Chem. Soc., Perkin Trans. 1, 1998, 3999-4004 -Reproduced by permission of The Royal Society of Chemistry (RSC)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2012-11-06 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Preparation and metal ion-binding properties of gramicidin S derivatives carrying picolinoyl groups on the ornithine side chains | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Yamada, Keiichi
× Yamada, Keiichi× Ozaki, Hirotaka× Kanda, Naoki× Yamamura, Hatsuo× Araki, Shuki× Kawai, Masao |
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著者別名 | ||||||
姓名 | 山村, 初雄 | |||||
著者別名 | ||||||
姓名 | 荒木, 修喜 | |||||
書誌情報 |
Journal of the Chemical Society. Perkin transactions 1 : organic and bio-organic chemistry. 巻 1998, 号 23, p. 3999-4004, 発行日 1998-01-01 |
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出版者 | ||||||
出版者 | Royal Society of Chemistry | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0300922X | |||||
書誌レコードID(NCID) | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA00695134 | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
DOI | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | DOI | |||||
関連識別子 | http://dx.doi.org/10.1039/A805468A | |||||
関連名称 | 10.1039/A805468A | |||||
内容記述 | ||||||
内容記述タイプ | Other | |||||
内容記述 | Derivatives of gramicidin S (GS) in which one or both of the two ornithine side chains were picolinoylated were prepared. The dipicolinoyl derivative [Orn(PyCO)2,2′]GS 1 formed a 1:1 complex with Cu2+ and Zn2+ in MeOH, while in the case of the monopicolinoyl derivative [Orn(Boc)2,Orn(PyCO)2′]GS (2) stepwise formation of 1:1 and 2:1 (2:Cu2+) complexes was observed. The formation constant of the Cu2+-mediated dimeric species of compound 2 was larger than those of the corresponding linear compounds possessing the partial structure of macrocycle 2. The corresponding tetra-N-methyl derivative [MeOrn(Boc)2,MeOrn(PyCO)2′,D-MePhe4,4′]GS 3 also showed lower stability of the 2:1 complex compared with compound 2, which suggested the presence of a β-sheet-type intermolecular H-bonding interaction between the two molecules of macrocycle 2 in the 2:1 complex. | |||||
フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf |