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Preparation and guest binding of novel β-cyclodextrin dimers linked with various sulfur-containing linker moieties
https://nitech.repo.nii.ac.jp/records/4611
https://nitech.repo.nii.ac.jp/records/4611475d7d01-3d9b-476b-8b4c-279101dd7c80
| 名前 / ファイル | ライセンス | アクション |
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本文_fulltext (285.2 kB)
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J. Chem. Soc., Perkin Trans. 1, 1999, 2943-2948 -Reproduced by permission of The Royal Society of Chemistry (RSC)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||||||||||||||||||||
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| 公開日 | 2012-11-06 | |||||||||||||||||||||||
| タイトル | ||||||||||||||||||||||||
| タイトル | Preparation and guest binding of novel β-cyclodextrin dimers linked with various sulfur-containing linker moieties | |||||||||||||||||||||||
| 言語 | en | |||||||||||||||||||||||
| 言語 | ||||||||||||||||||||||||
| 言語 | eng | |||||||||||||||||||||||
| 資源タイプ | ||||||||||||||||||||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||||||||||||||||
| 資源タイプ | journal article | |||||||||||||||||||||||
| 著者 |
Yamamura, Hatsuo
× Yamamura, Hatsuo
× Yamada, Shinichi
× Kono, Keiko
× Okuda, Nozomi
× Araki, Shuki
× Kobayashi, Kyoko
× Katakai, Ryoichi
× Kano, Kazuaki
× Kawai, Masao
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| 著者別名 | ||||||||||||||||||||||||
| 姓名 | 山村, 初雄 | |||||||||||||||||||||||
| 著者別名 | ||||||||||||||||||||||||
| 姓名 | 荒木, 修喜 | |||||||||||||||||||||||
| 書誌情報 |
en : Journal of the Chemical Society. Perkin transactions 1 : organic and bio-organic chemistry. 巻 1999, 号 20, p. 2943-2948, 発行日 1999-01-01 |
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| 出版者 | ||||||||||||||||||||||||
| 出版者 | Royal Society of Chemistry | |||||||||||||||||||||||
| 言語 | en | |||||||||||||||||||||||
| ISSN | ||||||||||||||||||||||||
| 収録物識別子タイプ | ISSN | |||||||||||||||||||||||
| 収録物識別子 | 0300-922X | |||||||||||||||||||||||
| item_10001_source_id_32 | ||||||||||||||||||||||||
| 収録物識別子タイプ | NCID | |||||||||||||||||||||||
| 収録物識別子 | AA00695134 | |||||||||||||||||||||||
| 出版タイプ | ||||||||||||||||||||||||
| 出版タイプ | VoR | |||||||||||||||||||||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||||||||||||||||||||
| item_10001_relation_34 | ||||||||||||||||||||||||
| 関連タイプ | isIdenticalTo | |||||||||||||||||||||||
| 識別子タイプ | DOI | |||||||||||||||||||||||
| 関連識別子 | http://dx.doi.org/10.1039/A905067A | |||||||||||||||||||||||
| 関連名称 | 10.1039/A905067A | |||||||||||||||||||||||
| 内容記述 | ||||||||||||||||||||||||
| 内容記述タイプ | Other | |||||||||||||||||||||||
| 内容記述 | Novel cyclodextrin dimers (1, 2, 3 and 4) whose cyclodextrins were linked with sulfur-containing linkers, namely a thiodipropanamide, a dithiodipropanamide, a thiodiethanamide, or a dithiodiethanamide linker, were synthesized by a reaction of 6-amino-6-deoxycycIoheptaose 7 with the corresponding dicarboxylic acids. For their preparation, dicyclohexylcarbodiimide, l-(3-dimethylaminopropyl)-3-ethylcarbodiimideand(benzotriazol-l-yloxy) tripyrroIidinophosphonium hexafluorophosphate were examined as coupling reagents. 'H NMR studies of the dimers suggested an intramolecular inclusion of the linker moiety to the cyclodextrin cavity, which affected the complexation of guest molecules. Dimer 4 was converted to another type of dimer 5 by reductive cleavage of the disulfide bond to generate thiol group-containing mononieric species followed by a substitution reaction with 6-O-tosyl derivative 6. | |||||||||||||||||||||||
| 言語 | en | |||||||||||||||||||||||
