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2D gel permeation chromatography (2D GPC) correlation studies of the growth process for perfluoro-octyltriethoxysilane polymer aggregates
https://nitech.repo.nii.ac.jp/records/5035
https://nitech.repo.nii.ac.jp/records/503554179c64-7b74-4c5b-8398-ef242e0f2e62
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
本文_fulltext (669.4 kB)
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Phys. Chem. Chem. Phys., 2002, 4, 1053-1061 -Reproduced by permission of the PCCP Owner Societies
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||||||||||||||
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| 公開日 | 2012-11-06 | |||||||||||||||||
| タイトル | ||||||||||||||||||
| タイトル | 2D gel permeation chromatography (2D GPC) correlation studies of the growth process for perfluoro-octyltriethoxysilane polymer aggregates | |||||||||||||||||
| 言語 | en | |||||||||||||||||
| 言語 | ||||||||||||||||||
| 言語 | eng | |||||||||||||||||
| 資源タイプ | ||||||||||||||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||||||||||
| 資源タイプ | journal article | |||||||||||||||||
| 著者 |
Izawa, Kenichi
× Izawa, Kenichi
× Ogasawara, Toshiaki
× Masuda, Hideki
× Okabayashi, Hirofumi
× O'Connord, Charmian
× Noda, Isao
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| 著者別名 | ||||||||||||||||||
| 姓名 | 増田, 秀樹 | |||||||||||||||||
| bibliographic_information |
en : Physical chemistry, chemical physics 巻 4, 号 6, p. 1053-1061, 発行日 2002-02-13 |
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| 出版者 | ||||||||||||||||||
| 出版者 | Royal Society of Chemistry | |||||||||||||||||
| 言語 | en | |||||||||||||||||
| ISSN | ||||||||||||||||||
| 収録物識別子タイプ | ISSN | |||||||||||||||||
| 収録物識別子 | 1463-9076 | |||||||||||||||||
| item_10001_source_id_32 | ||||||||||||||||||
| 収録物識別子タイプ | NCID | |||||||||||||||||
| 収録物識別子 | AA11301773 | |||||||||||||||||
| 出版タイプ | ||||||||||||||||||
| 出版タイプ | VoR | |||||||||||||||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||||||||||||||
| item_10001_relation_34 | ||||||||||||||||||
| 関連タイプ | isIdenticalTo | |||||||||||||||||
| 識別子タイプ | DOI | |||||||||||||||||
| 関連識別子 | http://dx.doi.org/10.1039/b107556j | |||||||||||||||||
| 関連名称 | 10.1039/b107556j | |||||||||||||||||
| 内容記述 | ||||||||||||||||||
| 内容記述タイプ | Other | |||||||||||||||||
| 内容記述 | A novel analytical technique, two-dimensional correlation gel permeation chromatography (2D correlation GPC), has been used to elucidate intricate details of the two-step (I and II) polymerization of 1H,1H,2H,2H-perfluoro-octyltriethoxysilane (PFOTES) catalyzed by 0.5, 1.0 and 2.0 M HCl・H2O over a time period of 600-14400 s. The 2D GPC correlation results demonstrate that each elution band (particularly, in step II) consists of two (reactive and nonreactive) components and that a higher HCl concentration enhances the correlation of the reactive component with other bands. It is suggested that rapid growth of the polymeric aggregates in step II may be caused by the appearance of these reactive components. | |||||||||||||||||
| 言語 | en | |||||||||||||||||
