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Performance of Tris(2-methyl-8-quinolinolato)aluminum as Fluorescent Anionophore
https://nitech.repo.nii.ac.jp/records/5154
https://nitech.repo.nii.ac.jp/records/5154b7765b80-35fe-4a6e-b645-3a2df1e8b4f9
名前 / ファイル | ライセンス | アクション |
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本文_fulltext (99.5 kB)
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2003 c The Japan Society for Analytical Chemistry
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2012-11-06 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Performance of Tris(2-methyl-8-quinolinolato)aluminum as Fluorescent Anionophore | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Yuchi, Akio
× Yuchi, Akio× Hiramatsu, Hiroaki× Ohara, Miyuki× Ohata, Nayumi |
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著者別名 | ||||||
姓名 | 湯地, 昭夫 | |||||
書誌情報 |
Analytical sciences : the international journal of the Japan Society for Analytical Chemistry 巻 19, 号 8, p. 1177-1181, 発行日 2003-08 |
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出版者 | ||||||
出版者 | The Japan Society for Analytical Chemistry | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 09106340 | |||||
書誌レコードID(NCID) | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA10500785 | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
DOI | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | DOI | |||||
関連識別子 | http://dx.doi.org/10.2116/analsci.19.1177 | |||||
関連名称 | 10.2116/analsci.19.1177 | |||||
内容記述 | ||||||
内容記述タイプ | Other | |||||
内容記述 | An X-ray crystallographic study demonstrated that the tris complex of Al3+ with 2-methyl-8-quinolinol (Hmq), [Al(mq)3], had a discrete octahedral geometry in a meridional configuration with respect to mq- the Al-N bonds were appreciably elongated. In organic solvents, the complex reacted with water to give a lower species of a μ-oxo dimer, [Al2O(mq)4], and a protonated ligand, depending on the concentrations of water and of excess ligand. None of Cl- Br- I- ClO4-, and CH3COO- showed any reactions with [Al(mq)3]. The anions having high affinities to Al3+, such as H2PO4- and F- replaced all the ligand. The anion having a lower affinity, HSO4-, exclusively formed a mixed-ligand complex of [Al(mq)2HSO4], which had a more intense fluorescence than the others. In contrast, the corresponding 8-quinolinol (Hq) complex, [Alq3], showed no reactions with any anions. | |||||
フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf |