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コバルト錯体担持固相の酸化還元による陰イオンの吸脱着制御
https://nitech.repo.nii.ac.jp/records/5622
https://nitech.repo.nii.ac.jp/records/56225e22ba90-4cc0-47d5-87d4-343a04d7d449
名前 / ファイル | ライセンス | アクション |
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本文_fulltext (587.8 kB)
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Copyright(2012) The Japan Society for Analytical Chemistry
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2013-07-01 | |||||
タイトル | ||||||
タイトル | コバルト錯体担持固相の酸化還元による陰イオンの吸脱着制御 | |||||
言語 | ||||||
言語 | jpn | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
その他(別言語等)のタイトル | ||||||
その他のタイトル | コバルト サクタイ タンジ コソウ ノ サンカ カンゲン ニヨル インイオン ノ キュウダッチャク セイギョ | |||||
その他(別言語等)のタイトル | ||||||
その他のタイトル | Control of Adsorption/Desorption of Anions Based on Redox of Solid Phase Coated with Cobalt Complexes | |||||
著者 |
安井, 孝志
× 安井, 孝志× 森部, 俊亮× 杉江, 俊輔× 小玉, 誠× 高田, 主岳× 湯地, 昭夫 |
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著者別名 | ||||||
姓名 | Yasui, Takashi | |||||
著者別名 | ||||||
姓名 | Takada, Kazutake | |||||
著者別名 | ||||||
姓名 | Yuchi, Akio | |||||
書誌情報 |
分析化学 = Japan analyst 巻 61, 号 3, p. 257-260, 発行日 2012-03-05 |
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出版者 | ||||||
出版者 | 日本分析化学会 | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 05251931 | |||||
書誌レコードID(NCID) | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AN00222633 | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
DOI | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | DOI | |||||
関連識別子 | http://dx.doi.org/10.2116/bunsekikagaku.61.257 | |||||
関連名称 | 10.2116/bunsekikagaku.61.257 | |||||
内容記述 | ||||||
内容記述タイプ | Other | |||||
内容記述 | The adsorption-desorption behaviors of hydrophobic anion on the solid phase coated with redox-active metal complexes (ML2+/0 ; M, CoIII/II ; L?, pyridylazo compounds) were investigated. The combination of a cobalt complex of poly vinyl phenol introduced with a 2-pyridylazo group and a solid-phase extraction cartridge packed with styrene-divinyl benzene copolymer sorbent showed the highest adsorption capacity for methyl orange as a hydrophobic anion. The percentage adsorption of methyl orange (1.0 μmol) on this solid phase was more than 99%, even in the presence of a 100-fold stoichiometric excess of coexisting anions (ClO4?, Cl?). Methyl orange molecules were desorbed by reducing the cobalt complexes in the solid phase with a 1.0 × 10?2 M ascorbic acid solution. | |||||
フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf |