{"created":"2023-05-15T12:34:50.486313+00:00","id":3559,"links":{},"metadata":{"_buckets":{"deposit":"9ca4d867-c6ca-4f2f-b556-235f1415f71e"},"_deposit":{"created_by":91,"id":"3559","owners":[91],"pid":{"revision_id":0,"type":"depid","value":"3559"},"status":"published"},"_oai":{"id":"oai:nitech.repo.nii.ac.jp:00003559","sets":["31"]},"author_link":["8710","8811","9695","9696","9656","9698","8710","8811"],"item_10001_alternative_title_24":{"attribute_name":"その他（別言語等）のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Performance of germanium (IV) complexes as anionophore","subitem_alternative_title_language":"en"}]},"item_10001_biblio_info_28":{"attribute_name":"bibliographic_information","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2004","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"9","bibliographicPageEnd":"1038","bibliographicPageStart":"1035","bibliographicVolumeNumber":"53","bibliographic_titles":[{"bibliographic_title":"分析化学 ","bibliographic_titleLang":"ja"},{"bibliographic_title":"Japan analyst","bibliographic_titleLang":"en"}]}]},"item_10001_description_36":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"A few germanium(IV) complexes were prepared and examined for the anionophore. A nitrilotriphenolato complex ([Ge2(ntp)2O]) with three coordinating phenolates around Ge(IV) showed a sub-Nernstian response (40 mV/decade) to fluoride in the range of 10-3?10-1 mol dm-3 as a carrier of ion-selective electrodes(ISEs). The dynamic range was extended to 10-4?10-1 mol dm-3 in the presence of cationic additives. Spectroscopic studies on the reaction of this complex with anions in dimethyl sulfoxide demonstrated the reaction stoichiometry of Ge(IV) : A- = 1 : 1 and the thermodynamic stability order of F- > CH3COO- > H2PO4-. The reaction selectivity agreed with that of potentiometry with ISEs. A bis(catecholato) complex with four phenolates showed no response to anions, and a bis(aminophenolato) complex with two phenolates was not stable enough in the reaction with anions.","subitem_description_language":"en","subitem_description_type":"Other"}]},"item_10001_full_name_27":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"8710","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"1000060270998","nameIdentifierScheme":"NRID","nameIdentifierURI":"http://rns.nii.ac.jp/nr/1000060270998"}],"names":[{"name":"Yasui, Takashi"}]},{"familyNames":[{"familyName":"Yuchi","familyNameLang":"en"},{"familyName":"湯地","familyNameLang":"ja"},{"familyName":"ユチ","familyNameLang":"ja-Kana"}],"givenNames":[{"givenName":"Akio","givenNameLang":"en"},{"givenName":"昭夫","givenNameLang":"ja"},{"givenName":"アキオ","givenNameLang":"ja-Kana"}],"nameIdentifiers":[{"nameIdentifier":"8811","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Yuchi, Akio","nameLang":"en"},{"name":"湯地, 昭夫","nameLang":"ja"},{"name":"ユチ, アキオ","nameLang":"ja-Kana"}]}]},"item_10001_publisher_29":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"日本分析化学会","subitem_publisher_language":"ja"}]},"item_10001_relation_34":{"attribute_name":"item_10001_relation_34","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"10.2116/bunsekikagaku.53.1035"}],"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"http://dx.doi.org/10.2116/bunsekikagaku.53.1035","subitem_relation_type_select":"DOI"}}]},"item_10001_source_id_30":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0525-1931","subitem_source_identifier_type":"ISSN"}]},"item_10001_source_id_32":{"attribute_name":"item_10001_source_id_32","attribute_value_mlt":[{"subitem_source_identifier":"AN00222633","subitem_source_identifier_type":"NCID"}]},"item_10001_version_type_33":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"宇野, 弘重"}],"nameIdentifiers":[{"nameIdentifier":"9695","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"鈴木, 崇嗣"}],"nameIdentifiers":[{"nameIdentifier":"9696","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"後藤, 康正"}],"nameIdentifiers":[{"nameIdentifier":"9656","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"伊藤, 慎祐"}],"nameIdentifiers":[{"nameIdentifier":"9698","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"安井, 孝志"},{"creatorName":"ヤスイ, タカシ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{"nameIdentifier":"8710","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"1000060270998","nameIdentifierScheme":"NRID","nameIdentifierURI":"http://rns.nii.ac.jp/nr/1000060270998"}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifierScheme":"ISNI","affiliationNameIdentifierURI":"http://www.isni.org/isni/"}],"affiliationNames":[{"affiliationNameLang":"ja"}]}],"creatorNames":[{"creatorName":"Yuchi, Akio","creatorNameLang":"en"},{"creatorName":"湯地, 昭夫","creatorNameLang":"ja"},{"creatorName":"ユチ, アキオ","creatorNameLang":"ja-Kana"}],"familyNames":[{"familyName":"Yuchi","familyNameLang":"en"},{"familyName":"湯地","familyNameLang":"ja"},{"familyName":"ユチ","familyNameLang":"ja-Kana"}],"givenNames":[{"givenName":"Akio","givenNameLang":"en"},{"givenName":"昭夫","givenNameLang":"ja"},{"givenName":"アキオ","givenNameLang":"ja-Kana"}],"nameIdentifiers":[{"nameIdentifier":"8811","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-01-20"}],"displaytype":"detail","filename":"JA 53_1035.pdf","filesize":[{"value":"287.2 kB"}],"format":"application/pdf","license_note":"c 2004 The Japan Society for Analytical Chemistry","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"本文_fulltext","url":"https://nitech.repo.nii.ac.jp/record/3559/files/JA 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