{"created":"2023-05-15T12:34:50.486313+00:00","id":3559,"links":{},"metadata":{"_buckets":{"deposit":"9ca4d867-c6ca-4f2f-b556-235f1415f71e"},"_deposit":{"created_by":3,"id":"3559","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"3559"},"status":"published"},"_oai":{"id":"oai:nitech.repo.nii.ac.jp:00003559","sets":["31"]},"author_link":["9656","9698","8811","8710","9695","9696"],"item_10001_alternative_title_24":{"attribute_name":"その他（別言語等）のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Performance of germanium (IV) complexes as anionophore"}]},"item_10001_biblio_info_28":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2004","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"9","bibliographicPageEnd":"1038","bibliographicPageStart":"1035","bibliographicVolumeNumber":"53","bibliographic_titles":[{"bibliographic_title":"分析化学 = Japan analyst"}]}]},"item_10001_description_36":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"A few germanium(IV) complexes were prepared and examined for the anionophore. A nitrilotriphenolato complex ([Ge2(ntp)2O]) with three coordinating phenolates around Ge(IV) showed a sub-Nernstian response (40 mV/decade) to fluoride in the range of 10-3?10-1 mol dm-3 as a carrier of ion-selective electrodes(ISEs). The dynamic range was extended to 10-4?10-1 mol dm-3 in the presence of cationic additives. Spectroscopic studies on the reaction of this complex with anions in dimethyl sulfoxide demonstrated the reaction stoichiometry of Ge(IV) : A- = 1 : 1 and the thermodynamic stability order of F- > CH3COO- > H2PO4-. The reaction selectivity agreed with that of potentiometry with ISEs. A bis(catecholato) complex with four phenolates showed no response to anions, and a bis(aminophenolato) complex with two phenolates was not stable enough in the reaction with anions.","subitem_description_type":"Other"}]},"item_10001_description_38":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_10001_full_name_27":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{},{}],"names":[{"name":"Yasui, Takashi"}]},{"nameIdentifiers":[{}],"names":[{"name":"Yuchi, Akio"}]}]},"item_10001_publisher_29":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"日本分析化学会"}]},"item_10001_relation_34":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"10.2116/bunsekikagaku.53.1035"}],"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"http://dx.doi.org/10.2116/bunsekikagaku.53.1035","subitem_relation_type_select":"DOI"}}]},"item_10001_source_id_30":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"05251931","subitem_source_identifier_type":"ISSN"}]},"item_10001_source_id_32":{"attribute_name":"書誌レコードID（NCID）","attribute_value_mlt":[{"subitem_source_identifier":"AN00222633","subitem_source_identifier_type":"NCID"}]},"item_10001_version_type_33":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"宇野, 弘重"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"鈴木, 崇嗣"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"後藤, 康正"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"伊藤, 慎祐"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"安井, 孝志"},{"creatorName":"ヤスイ, タカシ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{},{}]},{"creatorNames":[{"creatorName":"湯地, 昭夫"},{"creatorName":"ユチ, アキオ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-01-20"}],"displaytype":"detail","filename":"JA 53_1035.pdf","filesize":[{"value":"287.2 kB"}],"format":"application/pdf","license_note":"c 2004 The Japan Society for Analytical Chemistry","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"本文_fulltext","url":"https://nitech.repo.nii.ac.jp/record/3559/files/JA 53_1035.pdf"},"version_id":"02b1f9ac-2a6e-490f-a15a-86c4f5ac66c0"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"ゲルマニウム(IV)錯体のアニオノフォアとしての特性","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"ゲルマニウム(IV)錯体のアニオノフォアとしての特性"}]},"item_type_id":"10001","owner":"3","path":["31"],"pubdate":{"attribute_name":"公開日","attribute_value":"2012-11-06"},"publish_date":"2012-11-06","publish_status":"0","recid":"3559","relation_version_is_last":true,"title":["ゲルマニウム(IV)錯体のアニオノフォアとしての特性"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2023-05-15T13:25:50.000032+00:00"}