{"created":"2023-05-15T12:34:50.941415+00:00","id":3570,"links":{},"metadata":{"_buckets":{"deposit":"6901ce83-bff0-4cf2-b458-3382a6cce2f1"},"_deposit":{"created_by":3,"id":"3570","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"3570"},"status":"published"},"_oai":{"id":"oai:nitech.repo.nii.ac.jp:00003570","sets":["31"]},"author_link":["8811"],"item_10001_alternative_title_24":{"attribute_name":"その他（別言語等）のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Anion-Selective Electrodes Based on Polyvalent Metal Complexes"}]},"item_10001_biblio_info_28":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2006","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"2","bibliographicPageEnd":"94","bibliographicPageStart":"83","bibliographicVolumeNumber":"55","bibliographic_titles":[{"bibliographic_title":"分析化学 = Japan analyst"}]}]},"item_10001_description_36":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"ルイスの酸塩基反応を利用する陰イオン選択電極の中で特に高酸化数の金属イオンを含むものについて，著者のグループの研究を中心に解説した．単純なジアルキルスズ（IV）化合物がリン酸イオンやα-ヒドロキシカルボン酸に対して高い選択性を示すのは，コンディショニング中にこれらのイオンを含む多核の錯体が生成し，その錯体中では陰イオンが二つのSn(IV) と相互作用するとともにアルキル基によって溶媒から効果的に遮蔽されるためであることを明らかにした．これにより自己集合的な反応がイオン選択電極でも高い選択性を誘発する可能性を初めて示した．ジルコニウム（IV）-ポルフィリン錯体のうち，陽イオン性二量体は通常の陰イオンに対してイオン交換による応答を示すのに対して，中性単量体は配位子交換反応による応答を示した．中性単量体のカルボン酸応答は，補助配位子としての塩化物イオンが徐々に水酸化物イオンに置換されることにより弱まるが，塩酸との接触で可逆的に回復する．水酸化物に置換されたキャリヤーはクエン酸に対して高い選択性を示した．","subitem_description_type":"Other"}]},"item_10001_description_38":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_10001_full_name_27":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{}],"names":[{"name":"Yuchi, Akio"}]}]},"item_10001_publisher_29":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"日本分析化学会"}]},"item_10001_relation_34":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"10.2116/bunsekikagaku.55.83"}],"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"http://dx.doi.org/10.2116/bunsekikagaku.55.83","subitem_relation_type_select":"DOI"}}]},"item_10001_source_id_30":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"05251931","subitem_source_identifier_type":"ISSN"}]},"item_10001_source_id_32":{"attribute_name":"書誌レコードID（NCID）","attribute_value_mlt":[{"subitem_source_identifier":"AN00222633","subitem_source_identifier_type":"NCID"}]},"item_10001_version_type_33":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"湯地, 昭夫"},{"creatorName":"ユチ, アキオ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-01-20"}],"displaytype":"detail","filename":"JA 55_83.pdf","filesize":[{"value":"958.1 kB"}],"format":"application/pdf","license_note":"c 2006 The Japan Society for Analytical Chemistry","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"本文_fulltext","url":"https://nitech.repo.nii.ac.jp/record/3570/files/JA 55_83.pdf"},"version_id":"65c1f633-d3aa-409c-ba3c-2cfe4297fc4a"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"高酸化数金属錯体を用いる陰イオン選択電極","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"高酸化数金属錯体を用いる陰イオン選択電極"}]},"item_type_id":"10001","owner":"3","path":["31"],"pubdate":{"attribute_name":"公開日","attribute_value":"2012-11-06"},"publish_date":"2012-11-06","publish_status":"0","recid":"3570","relation_version_is_last":true,"title":["高酸化数金属錯体を用いる陰イオン選択電極"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2023-05-15T13:25:51.403781+00:00"}