{"created":"2023-05-15T12:34:51.604131+00:00","id":3586,"links":{},"metadata":{"_buckets":{"deposit":"8aac943c-54b4-456b-889d-c200a0982532"},"_deposit":{"created_by":3,"id":"3586","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"3586"},"status":"published"},"_oai":{"id":"oai:nitech.repo.nii.ac.jp:00003586","sets":["31"]},"author_link":["8811","9696","9816"],"item_10001_alternative_title_24":{"attribute_name":"その他（別言語等）のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"α-Hydroxycarboxylate Selectivity by Spontaneous Formation of Dimeric Dialkyltin (IV) Complexes in Membrane of Anion-Selective Electrode"}]},"item_10001_biblio_info_28":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2008","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"8","bibliographicPageEnd":"686","bibliographicPageStart":"683","bibliographicVolumeNumber":"57","bibliographic_titles":[{"bibliographic_title":"分析化学 = Japan analyst"}]}]},"item_10001_description_36":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"The liquid-membrane ion-selective electrode based on bis(pentafluorobenzyl)tin(IV) dibromide showed higher selectivities to α-hydroxycarboxylates than to other carboxylates without any hydroxyl group and those with a β-hydroxy group. The calibration curve for citrate was linear over a range of 10-4 to 10-2 mol dm-3 with a potential slope of -60 mV/decade. The equilibrium study on the complexation between dimethyltin(IV) and a series of carboxylates indicates the formation of stable, neutral and dimeric complexes only with α-hydroxycarboxylates, [(Me2Sn)2(H-1hc)2] {(H-1hc)-2 : species formed by deprotonation of α-hydroxycarboxylates (hc-) at α-OH groups}. The corresponding species may be spontaneously formed as electroactive species in the liquid membrane containing bis(pentafluorobenzyl)tin(IV) dibromide and acquire the selectivity to α-hydroxycarboxylates.","subitem_description_type":"Other"}]},"item_10001_description_38":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_10001_full_name_27":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{}],"names":[{"name":"Yuchi, Akio"}]}]},"item_10001_publisher_29":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"日本分析化学会"}]},"item_10001_relation_34":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"10.2116/bunsekikagaku.57.683"}],"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"http://dx.doi.org/10.2116/bunsekikagaku.57.683","subitem_relation_type_select":"DOI"}}]},"item_10001_source_id_30":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"05251931","subitem_source_identifier_type":"ISSN"}]},"item_10001_source_id_32":{"attribute_name":"書誌レコードID（NCID）","attribute_value_mlt":[{"subitem_source_identifier":"AN00222633","subitem_source_identifier_type":"NCID"}]},"item_10001_version_type_33":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"鈴木, 崇嗣"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"可児, 真平"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"湯地, 昭夫"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-01-20"}],"displaytype":"detail","filename":"JA 57_683.pdf","filesize":[{"value":"780.8 kB"}],"format":"application/pdf","license_note":"c 2008 The Japan Society for Analytical Chemistry","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"本文_fulltext","url":"https://nitech.repo.nii.ac.jp/record/3586/files/JA 57_683.pdf"},"version_id":"c4ebce5c-feae-4de2-a258-cc5ef37e5bad"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"陰イオン選択性電極感応膜中における複核ジアルキルスズ（IV）錯体の生成によるα-ヒドロキシカルボン酸選択性","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"陰イオン選択性電極感応膜中における複核ジアルキルスズ（IV）錯体の生成によるα-ヒドロキシカルボン酸選択性"}]},"item_type_id":"10001","owner":"3","path":["31"],"pubdate":{"attribute_name":"公開日","attribute_value":"2012-11-06"},"publish_date":"2012-11-06","publish_status":"0","recid":"3586","relation_version_is_last":true,"title":["陰イオン選択性電極感応膜中における複核ジアルキルスズ（IV）錯体の生成によるα-ヒドロキシカルボン酸選択性"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-05-16T15:03:37.513660+00:00"}