{"created":"2023-05-15T12:34:59.948870+00:00","id":3783,"links":{},"metadata":{"_buckets":{"deposit":"04547844-7568-4f52-b42a-29acfd05675f"},"_deposit":{"created_by":3,"id":"3783","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"3783"},"status":"published"},"_oai":{"id":"oai:nitech.repo.nii.ac.jp:00003783","sets":["31"]},"author_link":["10534","10536"],"item_10001_biblio_info_28":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1984-01-01","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"972","bibliographicPageStart":"969","bibliographicVolumeNumber":"1984","bibliographic_titles":[{"bibliographic_title":"Journal of the Chemical Society. Perkin transactions 1"}]}]},"item_10001_description_36":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"Regio- and stereo-chemistry of transition-metal-catalysed Grignard reactions of secondary allylic phosphates have been investigated. Best results for regioselective carbon-carbon bond formation at the γ-position of secondary allylic phosphates were attained when copper(I) iodide was used as the catalyst. The naturally occurring monoterpene alcohols, geraniol and the sex pheromone of the African Monarch, were synthesized as a demonstration of the synthetic utility of the newly developed coupling reaction.","subitem_description_type":"Other"}]},"item_10001_description_38":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_10001_full_name_27":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{}],"names":[{"name":"荒木, 修喜"}]}]},"item_10001_publisher_29":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Royal Society of Chemistry"}]},"item_10001_relation_34":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"10.1039/P19840000969"}],"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"http://dx.doi.org/10.1039/P19840000969","subitem_relation_type_select":"DOI"}}]},"item_10001_source_id_30":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0300922X","subitem_source_identifier_type":"ISSN"}]},"item_10001_source_id_32":{"attribute_name":"書誌レコードID（NCID）","attribute_value_mlt":[{"subitem_source_identifier":"AA00695134","subitem_source_identifier_type":"NCID"}]},"item_10001_version_type_33":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Araki, Shuki","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Butsugan, Yasuo","creatorNameLang":"en"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-01-23"}],"displaytype":"detail","filename":"JCSP 1984_969.pdf","filesize":[{"value":"606.1 kB"}],"format":"application/pdf","license_note":"J. CHEM. SOC. PERKIN TRANS. I 1984, 969-972 - Reproduced by permission of The Royal Society of Chemistry (RSC)","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"本文_fulltext","url":"https://nitech.repo.nii.ac.jp/record/3783/files/JCSP 1984_969.pdf"},"version_id":"1984318e-46d5-4332-a741-f9b425a52782"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Transition-metal-catalysed Grignard reaction of secondary allylic phosphates","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Transition-metal-catalysed Grignard reaction of secondary allylic phosphates","subitem_title_language":"en"}]},"item_type_id":"10001","owner":"3","path":["31"],"pubdate":{"attribute_name":"公開日","attribute_value":"2012-11-06"},"publish_date":"2012-11-06","publish_status":"0","recid":"3783","relation_version_is_last":true,"title":["Transition-metal-catalysed Grignard reaction of secondary allylic phosphates"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-05-16T14:59:54.329594+00:00"}