@article{oai:nitech.repo.nii.ac.jp:00003815,
 author = {Yuchi, Akio and Wada, Hiroko and Nakagawa, Genkichi},
 issue = {1},
 journal = {Analytical sciences : the international journal of the Japan Society for Analytical Chemistry},
 month = {Apr},
 note = {The potential response of copper(II), lead and cadmium ion-selective electrodes was studied in ligand buffers which contain a complex ML(M:Cu2+, Pb2+ or Cd2+), a ligand L and an excess of a second metal N. By measuring [M] with the ion-selective electrode, the ratio of the stability constants, KML/KNL was determined. The effects of pH, the second metal ion N and the ratio of [N]/[NL] on the electrode response were studied in detail. The KML/KNL values obtained for EDTA were in good agreement with those calculated from KML and KNL in the literature. The stability constants of N-hydroxyethylenediamine-N, N′, N′-triacetate complexes were determined successfully. These logarithmic values of KNL were found: Pb2+, 15.59; Zn2+, 14.59; Co2+, 14.49; Cd2+, 14.24; Mn2+, 11.41. These results show that the method is very useful for the determination of the stability constants of complexes with metal ions for which suitable ion-selective electrodes are not available., application/pdf},
 pages = {19--22},
 title = {Use of Ligand Buffers in the Determination of the Stability Constants of Metal Complexes with Ion-Selective Electrodes},
 volume = {1},
 year = {1985}
}