{"created":"2023-05-15T12:35:01.306487+00:00","id":3815,"links":{},"metadata":{"_buckets":{"deposit":"10b0522d-d67f-4d50-adbd-35be4773786e"},"_deposit":{"created_by":3,"id":"3815","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"3815"},"status":"published"},"_oai":{"id":"oai:nitech.repo.nii.ac.jp:00003815","sets":["31"]},"author_link":["9542","9541","8811"],"item_10001_biblio_info_28":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1985-04","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1","bibliographicPageEnd":"22","bibliographicPageStart":"19","bibliographicVolumeNumber":"1","bibliographic_titles":[{"bibliographic_title":"Analytical sciences : the international journal of the Japan Society for Analytical Chemistry"}]}]},"item_10001_description_36":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"The potential response of copper(II), lead and cadmium ion-selective electrodes was studied in ligand buffers which contain a complex ML(M:Cu2+, Pb2+ or Cd2+), a ligand L and an excess of a second metal N. By measuring [M] with the ion-selective electrode, the ratio of the stability constants, KML/KNL was determined. The effects of pH, the second metal ion N and the ratio of [N]/[NL] on the electrode response were studied in detail. The KML/KNL values obtained for EDTA were in good agreement with those calculated from KML and KNL in the literature. The stability constants of N-hydroxyethylenediamine-N, N′, N′-triacetate complexes were determined successfully. These logarithmic values of KNL were found: Pb2+, 15.59; Zn2+, 14.59; Co2+, 14.49; Cd2+, 14.24; Mn2+, 11.41. These results show that the method is very useful for the determination of the stability constants of complexes with metal ions for which suitable ion-selective electrodes are not available.","subitem_description_type":"Other"}]},"item_10001_description_38":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_10001_full_name_27":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{}],"names":[{"name":"湯地, 昭夫"}]}]},"item_10001_publisher_29":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"The Japan Society for Analytical Chemistry"}]},"item_10001_relation_34":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"10.2116/analsci.1.19"}],"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"http://dx.doi.org/10.2116/analsci.1.19","subitem_relation_type_select":"DOI"}}]},"item_10001_source_id_30":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"09106340","subitem_source_identifier_type":"ISSN"}]},"item_10001_source_id_32":{"attribute_name":"書誌レコードID（NCID）","attribute_value_mlt":[{"subitem_source_identifier":"AA10500785","subitem_source_identifier_type":"NCID"}]},"item_10001_version_type_33":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Yuchi, Akio","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Wada, Hiroko","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Nakagawa, Genkichi","creatorNameLang":"en"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-01-23"}],"displaytype":"detail","filename":"AS 1_19.pdf","filesize":[{"value":"221.3 kB"}],"format":"application/pdf","license_note":"1985 c The Japan Society for Analytical Chemistry","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"本文_fulltext","url":"https://nitech.repo.nii.ac.jp/record/3815/files/AS 1_19.pdf"},"version_id":"0637eab6-6930-4a0c-b273-045e948ec7f9"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Use of Ligand Buffers in the Determination of the Stability Constants of Metal Complexes with Ion-Selective Electrodes","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Use of Ligand Buffers in the Determination of the Stability Constants of Metal Complexes with Ion-Selective Electrodes","subitem_title_language":"en"}]},"item_type_id":"10001","owner":"3","path":["31"],"pubdate":{"attribute_name":"公開日","attribute_value":"2012-11-06"},"publish_date":"2012-11-06","publish_status":"0","recid":"3815","relation_version_is_last":true,"title":["Use of Ligand Buffers in the Determination of the Stability Constants of Metal Complexes with Ion-Selective Electrodes"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-05-16T14:59:11.838984+00:00"}