@article{oai:nitech.repo.nii.ac.jp:00003845, author = {Sugimoto, Hiroshi and Mori, Masayasu and Masuda, Hideki and Taga, Toru}, issue = {12}, journal = {Journal of the Chemical Society. Chemical communications}, month = {Jan}, note = {Controlled potential electrolysis of the dilithium salt of phthalocyanine, Li2(pc2-), at 0.15 V vs. saturated calomel electrode in acetonitrile gave a lithium complex of the phthalocyanine radical, the crystal structure of which shows that it contains a unit cell with four nearly planar Li(pc・-) molecules of S4 symmetry, stacked metal-over-metal with an Li-Li spacing of 3.245(2)A, and staggered by 38.7(3)°; its effective magnetic moment decreased from the room temperature value of 1.3 μB to 1.0 μB at 150 K, but upon further cooling it increased to approach the free-spin value., application/pdf}, pages = {962--963}, title = {Synthesis and molecular structure of a lithium complex of the phthalocyanine radical}, volume = {1986}, year = {1986} }