{"created":"2023-05-15T12:35:04.280969+00:00","id":3884,"links":{},"metadata":{"_buckets":{"deposit":"7aea941b-a133-4b98-87df-9a63baf3f1d9"},"_deposit":{"created_by":3,"id":"3884","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"3884"},"status":"published"},"_oai":{"id":"oai:nitech.repo.nii.ac.jp:00003884","sets":["31"]},"author_link":["11090","8785","11091","10504","11087","11089","11093","11088"],"item_10001_biblio_info_28":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1987-01-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"5","bibliographicPageEnd":"611","bibliographicPageStart":"607","bibliographicVolumeNumber":"1987","bibliographic_titles":[{"bibliographic_title":"Journal of the Chemical Society. Perkin transactions 2"}]}]},"item_10001_description_36":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"The rate constants of both acylation and deacylation in the cleavage of the enantiomers of amino acid p-nitrophenyl esters catalysed by optically active catalysts containing the imidazolyl group have been determined in the presence of surfactant micelles at pH 7.30 in 0.02M-phosphate buffer and 25 °C. The kinetic analysis suggests a nucleophilic mechanism which involves acylation followed by deacylation at the imidazolyl group. Micellar  catalysis in deacylation as well as acylation is examined in terms of the rate constants and stereoselectivity. The structural effects of catalysts and substrates and the stereoselective reaction mechanism are discussed.","subitem_description_type":"Other"}]},"item_10001_description_38":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_10001_full_name_27":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{},{}],"names":[{"name":"中西, 英二"}]},{"nameIdentifiers":[{}],"names":[{"name":"南後, 守"}]}]},"item_10001_publisher_29":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Royal Society of Chemistry"}]},"item_10001_relation_34":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"10.1039/P29870000607"}],"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"http://dx.doi.org/10.1039/P29870000607","subitem_relation_type_select":"DOI"}}]},"item_10001_source_id_30":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1472779X","subitem_source_identifier_type":"ISSN"}]},"item_10001_source_id_32":{"attribute_name":"書誌レコードID（NCID）","attribute_value_mlt":[{"subitem_source_identifier":"AA11413697","subitem_source_identifier_type":"NCID"}]},"item_10001_version_type_33":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Ihara, Yasuji","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Okamoto, Mari","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kawamura, Yoko","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Nakanishi, Eiji","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Nango, Mamoru","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Koga, Joichi","creatorNameLang":"en"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-01-23"}],"displaytype":"detail","filename":"JCSP 1987_607.pdf","filesize":[{"value":"643.8 kB"}],"format":"application/pdf","license_note":"J. CHEM. SOC. PERKIN TRANS. II 1987 , 607-611 -Reproduced by permission of The Royal Society of Chemistry (RSC)","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"本文_fulltext","url":"https://nitech.repo.nii.ac.jp/record/3884/files/JCSP 1987_607.pdf"},"version_id":"4fa20c4b-b7ec-4111-8bdd-99d22352a1f2"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Stereoselective micellar catalysis. Part 5. Deacylation behaviour in the cleavage of enantiomeric esters by optically active catalysts containing the imidazolyl group","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Stereoselective micellar catalysis. Part 5. Deacylation behaviour in the cleavage of enantiomeric esters by optically active catalysts containing the imidazolyl group","subitem_title_language":"en"}]},"item_type_id":"10001","owner":"3","path":["31"],"pubdate":{"attribute_name":"公開日","attribute_value":"2012-11-06"},"publish_date":"2012-11-06","publish_status":"0","recid":"3884","relation_version_is_last":true,"title":["Stereoselective micellar catalysis. Part 5. Deacylation behaviour in the cleavage of enantiomeric esters by optically active catalysts containing the imidazolyl group"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-05-16T14:57:12.167300+00:00"}