{"created":"2023-05-15T12:35:19.856351+00:00","id":4188,"links":{},"metadata":{"_buckets":{"deposit":"369cddf2-c7fc-49ca-9239-dfa8e4203019"},"_deposit":{"created_by":3,"id":"4188","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"4188"},"status":"published"},"_oai":{"id":"oai:nitech.repo.nii.ac.jp:00004188","sets":["31"]},"author_link":["12465","9541","8811","9542"],"item_10001_biblio_info_28":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1993-01-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"2","bibliographicPageEnd":"222","bibliographicPageStart":"219","bibliographicVolumeNumber":"118","bibliographic_titles":[{"bibliographic_title":"Analyst"}]}]},"item_10001_description_36":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"An equimolar mixture of zirconium(IV) and Semi-Xylenol Orange (SXO) reacts rapidly with fluoride ion at pH 2 to cause an increase in absorbance at about 530 nm. The calibration graph was linear up to 1×10-5 mol dm-3. In a flow injection system, a detection limit (signal-to-noise ratio=3) of 2.5×10-7 mol dm-3 was obtained with a sample throughput of 60 h-1. Potentiometric studies of this reaction system with a fluoride ion-selective electrode demonstrated that an increase in absorbance can be ascribed to the coordination of the phenolic oxygen of SXO on the reaction of a partly hydrolysed Zr-SXO complex with fluoride ion to give the mixed ligand complex.","subitem_description_type":"Other"}]},"item_10001_description_38":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_10001_full_name_27":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{}],"names":[{"name":"湯地, 昭夫"}]}]},"item_10001_publisher_29":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Royal Society of Chemistry"}]},"item_10001_relation_34":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"10.1039/AN9931800219"}],"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"http://dx.doi.org/10.1039/AN9931800219","subitem_relation_type_select":"DOI"}}]},"item_10001_source_id_30":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"00032654","subitem_source_identifier_type":"ISSN"}]},"item_10001_source_id_32":{"attribute_name":"書誌レコードID（NCID）","attribute_value_mlt":[{"subitem_source_identifier":"AA00524823","subitem_source_identifier_type":"NCID"}]},"item_10001_version_type_33":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Yuchi, Akio","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Hokari, Norihisa","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Wada, Hiroko","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Nakagawa, Genkichi","creatorNameLang":"en"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-01-23"}],"displaytype":"detail","filename":"ANA 118_219.pdf","filesize":[{"value":"529.0 kB"}],"format":"application/pdf","license_note":"Analyst, February 1993, Vol. 118, 219-222 -Reproduced by permission of The Royal Society of Chemistry (RSC)","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"本文_fulltext","url":"https://nitech.repo.nii.ac.jp/record/4188/files/ANA 118_219.pdf"},"version_id":"7f3c3cf2-5815-46cb-979d-0a2dc89c969c"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Semi-xylenol orange complex of zirconium(IV) as a photometric reagent system for fluoride based on mixed ligand complex formation","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Semi-xylenol orange complex of zirconium(IV) as a photometric reagent system for fluoride based on mixed ligand complex formation","subitem_title_language":"en"}]},"item_type_id":"10001","owner":"3","path":["31"],"pubdate":{"attribute_name":"公開日","attribute_value":"2012-11-06"},"publish_date":"2012-11-06","publish_status":"0","recid":"4188","relation_version_is_last":true,"title":["Semi-xylenol orange complex of zirconium(IV) as a photometric reagent system for fluoride based on mixed ligand complex formation"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-05-16T14:51:05.188364+00:00"}