{"created":"2023-05-15T12:35:22.814071+00:00","id":4258,"links":{},"metadata":{"_buckets":{"deposit":"3819db01-f3c7-4ee8-ad27-ffc8d0c763ac"},"_deposit":{"created_by":91,"id":"4258","owners":[91],"pid":{"revision_id":0,"type":"depid","value":"4258"},"status":"published"},"_oai":{"id":"oai:nitech.repo.nii.ac.jp:00004258","sets":["31"]},"author_link":["8590","8590","12780","12781","12782","12783"],"item_10001_biblio_info_28":{"attribute_name":"bibliographic_information","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1994-01-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"14","bibliographicPageEnd":"2070","bibliographicPageStart":"2065","bibliographicVolumeNumber":"1994","bibliographic_titles":[{"bibliographic_title":"Journal of the Chemical Society. Dalton transactions","bibliographic_titleLang":"en"}]}]},"item_10001_description_36":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"The donor-acceptor molecular complexes of bis(1-methyliminomethyl-2-naphtholato)copper(II)[CuL2] with 7,7,8,8-tetracyanoquinodimethane (tcnq), tetrachloro-1,4-benzoquinone (tcbq) and 1,3,5-trinitrobenzene (tnb), as well as the parent complex have been subjected to single-crystal X-ray diffraction analysis. The molecular complexes [CuL2]・2tcnq and [CuL2]・2tnb crystallize in the triclinic space group P and [CuL2]・2tcbq crystallizes in the monoclinic space group P21/n, the copper atoms of all complexes being positioned at an inversion centre. The molecular complexes showed a typical π-π type structure consisting of alternately stacked π-electron donor (naphthalene moiety of copper complex) and π-electron acceptor (tcnq, tcbq and tnb) along the c axis (needle axis). The ESR spectrum for a copper(II) doped sample of diamagnetic [NiL2]・2tnb showed simple copper quartet lines due to I=. The X-ray analyses indicated that the donor-acceptor interaction operating along the c axis gives a one-dimensional structure consisting of alternately stacked donor and acceptor molecules, but no distinct two-dimensional interaction.","subitem_description_language":"en","subitem_description_type":"Other"}]},"item_10001_full_name_27":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"8590","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"1000070293743","nameIdentifierScheme":"NRID","nameIdentifierURI":"http://rns.nii.ac.jp/nr/1000070293743"}],"names":[{"name":"塩塚, 理仁"}]}]},"item_10001_publisher_29":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Royal Society of Chemistry","subitem_publisher_language":"en"}]},"item_10001_relation_34":{"attribute_name":"item_10001_relation_34","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"10.1039/DT9940002065"}],"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"http://dx.doi.org/10.1039/DT9940002065","subitem_relation_type_select":"DOI"}}]},"item_10001_source_id_30":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0300-9246","subitem_source_identifier_type":"ISSN"}]},"item_10001_source_id_32":{"attribute_name":"item_10001_source_id_32","attribute_value_mlt":[{"subitem_source_identifier":"AA00695101","subitem_source_identifier_type":"NCID"}]},"item_10001_version_type_33":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Shiotsuka, Michito","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"8590","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"1000070293743","nameIdentifierScheme":"NRID","nameIdentifierURI":"http://rns.nii.ac.jp/nr/1000070293743"}]},{"creatorNames":[{"creatorName":"Okaue, Yoshihiro","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"12780","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Matsumoto, Naohide","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"12781","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Okawa, Hisashi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"12782","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Isobe, Toshiyuki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"12783","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-01-23"}],"displaytype":"detail","filename":"JCSD 1994_2065.pdf","filesize":[{"value":"645.1 kB"}],"format":"application/pdf","license_note":"J. CHEM. SOC. DALTON TRANS. 1994, 2065-Reproduced by permission of The Royal Society of Chemistry (RSC)","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"本文_fulltext","url":"https://nitech.repo.nii.ac.jp/record/4258/files/JCSD 1994_2065.pdf"},"version_id":"a5c156fd-514b-4442-a0f4-0d61098a826d"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"item_resource_type","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Crystal structures and single-crystal electron spin resonance spectra of π-π Type molecular complexes of bis(1-methyliminomethyl-2-naphtholato)copper(II)","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Crystal structures and single-crystal electron spin resonance spectra of π-π Type molecular complexes of bis(1-methyliminomethyl-2-naphtholato)copper(II)","subitem_title_language":"en"}]},"item_type_id":"10001","owner":"91","path":["31"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2012-11-07"},"publish_date":"2012-11-07","publish_status":"0","recid":"4258","relation_version_is_last":true,"title":["Crystal structures and single-crystal electron spin resonance spectra of π-π Type molecular complexes of bis(1-methyliminomethyl-2-naphtholato)copper(II)"],"weko_creator_id":"91","weko_shared_id":-1},"updated":"2025-03-14T00:40:41.618217+00:00"}