@article{oai:nitech.repo.nii.ac.jp:00004266, author = {Ebihara, Masahiro and Tokoro, Kenji and Maeda, Minobu and Ogami, Masaki and Imaeda, Kaori and Sakurai, Kenji and Masuda, Hideki and Kawamura, Takashi}, issue = {24}, journal = {Journal of the Chemical Society. Dalton transactions}, month = {Jan}, note = {The mixed-metal complexes [M3(S2CNR2)6M′ 2]2+ (M = Pt or Pd; M′ = Ag or Cu; R = Et, Pri, Prn, Bun or C6H11) have been prepared quantitatively upon mixing stoichiometric amounts of [M(S2CNR2)2 and Ag+ or [Cu(MeCN)4]+ in dichloromethane. The structures of nine of them have been determined and are classified into three types: one polymer and two discrete ion structures. Comparison of the structures indicates the existence of a bonding interaction between M and M′ that is greater for Pt than Pd and for Ag than Cu. The strong bonding interaction between the Pt and Ag atoms is also supported by the 195Pt-107,109Ag coupling constant of 194 Hz for [Pt3(S2CNBun2)6Ag 2]2+., application/pdf}, pages = {3621--3635}, title = {Bonding interaction between Group 10 and 11 metals. Synthesis, structure and properties of [M3(S2CNR2)6M′2]2+(M = Pt or Pd; M′= Ag or Cu; R = Et, Pri, Prn, Bun or C6H11)}, volume = {1994}, year = {1994} }