{"created":"2023-05-15T12:35:27.161432+00:00","id":4362,"links":{},"metadata":{"_buckets":{"deposit":"c916e98b-ba88-49c7-bbcd-8c7c5dbbaae7"},"_deposit":{"created_by":3,"id":"4362","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"4362"},"status":"published"},"_oai":{"id":"oai:nitech.repo.nii.ac.jp:00004362","sets":["31"]},"author_link":["13281","13283","8696","13284"],"item_10001_biblio_info_28":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1995-08","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"4","bibliographicPageEnd":"562","bibliographicPageStart":"557","bibliographicVolumeNumber":"11","bibliographic_titles":[{"bibliographic_title":"Analytical sciences : the international journal of the Japan Society for Analytical Chemistry"}]}]},"item_10001_description_36":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"The bis(trifluoromethanesulfonato)nickel(II) complex with two 2, 2′-bipyridine (bpy), [Ni(bpy)2(CF3SO3)2] (1), and the mono(trifluoromethanesulfonato)palladium(II) complex with bis(2-diphenylphosphinoethyl)phenylphosphine (p3), [Pd(p3)(CF3SO3)](CF3SO3)・C6H6 (2), were isolated. The crystal structures for 1 and 2 have been determined by an X-ray crystal structure analysis. Complex 1 crystallizes in monoclinic space group Aa with a=18.55(1), b=14.48(1), c=9.941(7)A, β=101.98(3)°, and Z=4. Complex 2 crystallizes in the monoclinic space group P21/n with a=17.211(5), b=27.175(7), c=9.962(2)A, β=105.66(2)°, and Z=4. The crystal of 1 contains a distorted octahedral nickel(II) complex with a cis arrangement, and the crystal of 2 contains a distorted square-planar palladium(II) complex. The metal-oxygen bond distances for triflate (CF3SO3-), (2.135(5) and 2.148(4)A for 1 and 2.126(7)A for 2), are comparable to those for the other oxygen donors. Three S-O bond distances in the coordinated triflate are close to one another. The stability of the metal-oxygen bond is discussed in terms of the electronic property of triflate.","subitem_description_type":"Other"}]},"item_10001_description_38":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_10001_full_name_27":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{}],"names":[{"name":"柳生, 剛義"}]}]},"item_10001_publisher_29":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"The Japan Society for Analytical Chemistry"}]},"item_10001_relation_34":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"10.2116/analsci.11.557"}],"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"http://dx.doi.org/10.2116/analsci.11.557","subitem_relation_type_select":"DOI"}}]},"item_10001_source_id_30":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"09106340","subitem_source_identifier_type":"ISSN"}]},"item_10001_source_id_32":{"attribute_name":"書誌レコードID（NCID）","attribute_value_mlt":[{"subitem_source_identifier":"AA10500785","subitem_source_identifier_type":"NCID"}]},"item_10001_version_type_33":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Aizawa, Shinichi","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Yagyu, Takeyoshi","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kato, Kaoru","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Funahashi, Shigenobu","creatorNameLang":"en"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-01-23"}],"displaytype":"detail","filename":"AS 11_557.pdf","filesize":[{"value":"400.6 kB"}],"format":"application/pdf","license_note":"1995 c The Japan Society for Analytical Chemistry","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"本文_fulltext","url":"https://nitech.repo.nii.ac.jp/record/4362/files/AS 11_557.pdf"},"version_id":"7264cd4f-681f-4da0-9dfd-0f4216ed9f11"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Crystal Structures of Trifluoromethanesulfonato Complexes of Nickel(II) and Palladium(II), [Ni(bpy)2(CF3SO3)2] and [Pd(triphosphine)(CF3SO3)](CF3SO3)・C6H6, and Characterization of the Coordination Ability of CF3SO3-","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Crystal Structures of Trifluoromethanesulfonato Complexes of Nickel(II) and Palladium(II), [Ni(bpy)2(CF3SO3)2] and [Pd(triphosphine)(CF3SO3)](CF3SO3)・C6H6, and Characterization of the Coordination Ability of CF3SO3-","subitem_title_language":"en"}]},"item_type_id":"10001","owner":"3","path":["31"],"pubdate":{"attribute_name":"公開日","attribute_value":"2012-11-06"},"publish_date":"2012-11-06","publish_status":"0","recid":"4362","relation_version_is_last":true,"title":["Crystal Structures of Trifluoromethanesulfonato Complexes of Nickel(II) and Palladium(II), [Ni(bpy)2(CF3SO3)2] and [Pd(triphosphine)(CF3SO3)](CF3SO3)・C6H6, and Characterization of the Coordination Ability of CF3SO3-"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2023-05-16T14:20:55.490610+00:00"}