{"created":"2023-05-15T12:35:31.246946+00:00","id":4459,"links":{},"metadata":{"_buckets":{"deposit":"44e27d0b-97e7-4041-bbf1-134db832f079"},"_deposit":{"created_by":3,"id":"4459","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"4459"},"status":"published"},"_oai":{"id":"oai:nitech.repo.nii.ac.jp:00004459","sets":["31"]},"author_link":["8802","13744","13742","5128","11688"],"item_10001_biblio_info_28":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1997-01-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1","bibliographicPageEnd":"146","bibliographicPageStart":"143","bibliographicVolumeNumber":"93","bibliographic_titles":[{"bibliographic_title":"Journal of the Chemical Society. Faraday transactions."}]}]},"item_10001_description_36":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"N-Acetylglycine oligomer ethyl esters (residue number, n=3-9) and selectively C-deuteriated oligomer acid types (n=3, 4) have been synthesized. Two crystalline modifications, the A- and B-series [which correspond to polyglycine (PG) II and I in structure, respectively] have been prepared. For the two series of oligomers, the intermolecular hydrogen-bond distance (RN・・・O) and segmental mobility were evaluated using 13C CP MAS and 2H NMR spectra. The results showed that the RN・・・O values for the A- and B-series of oligomer ethyl esters closely correspond to those of PGII and PGI, respectively, and that for the two series of C-deuteriated oligomers segmental mobilities of the CH2 groups of both the N- and C-terminal residues are more restricted than those of the methylenes sandwiched between the terminal residues.","subitem_description_type":"Other"}]},"item_10001_description_38":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_10001_full_name_27":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{}],"names":[{"name":"吉野, 明広"}]}]},"item_10001_publisher_29":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Royal Society of Chemistry"}]},"item_10001_relation_34":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"10.1039/A605775F"}],"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"http://dx.doi.org/10.1039/A605775F","subitem_relation_type_select":"DOI"}}]},"item_10001_source_id_30":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"09565000","subitem_source_identifier_type":"ISSN"}]},"item_10001_source_id_32":{"attribute_name":"書誌レコードID（NCID）","attribute_value_mlt":[{"subitem_source_identifier":"AA10743481","subitem_source_identifier_type":"NCID"}]},"item_10001_version_type_33":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Etori, Hideki","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Yoshino, Akihiro","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Watanabe, Kazuya","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Okabayashi, Hirofumi","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Oshima, Kunihiro","creatorNameLang":"en"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-01-23"}],"displaytype":"detail","filename":"JCSF 93_143.pdf","filesize":[{"value":"290.5 kB"}],"format":"application/pdf","license_note":"J. Chem. Soc., Faraday T rans., 1997, 93(1), 143-146 - Reproduced by permission of The Royal Society of Chemistry (RSC)","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"本文_fulltext","url":"https://nitech.repo.nii.ac.jp/record/4459/files/JCSF 93_143.pdf"},"version_id":"2027b3a9-e15b-4fc5-8e1c-188441dda844"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"13C and 2H NMR  studies of N-acetylglycine oligomer ethyl esters (residue number, n = 3-9) and selectively C-deuteriated oligomer acid types (n = 3, 4): Intermolecular hydrogen-bonding distance and segmental mobility","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"13C and 2H NMR  studies of N-acetylglycine oligomer ethyl esters (residue number, n = 3-9) and selectively C-deuteriated oligomer acid types (n = 3, 4): Intermolecular hydrogen-bonding distance and segmental mobility","subitem_title_language":"en"}]},"item_type_id":"10001","owner":"3","path":["31"],"pubdate":{"attribute_name":"公開日","attribute_value":"2012-11-06"},"publish_date":"2012-11-06","publish_status":"0","recid":"4459","relation_version_is_last":true,"title":["13C and 2H NMR  studies of N-acetylglycine oligomer ethyl esters (residue number, n = 3-9) and selectively C-deuteriated oligomer acid types (n = 3, 4): Intermolecular hydrogen-bonding distance and segmental mobility"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2023-05-16T14:19:13.409356+00:00"}