@article{oai:nitech.repo.nii.ac.jp:00004865, author = {Nakamura, Shuichi and Kuroyanagi, Masayuki and Watanabe, Yoshihiko and Toru, Takeshi}, issue = {18}, journal = {Journal of the Chemical Society. Perkin transactions 1}, month = {Sep}, note = {Reduction of γ-keto sulfoxides bearing the 2,4,6-triisopropylphenyl group with DIBAL gives γ-hydroxy sulfoxides with high stereoselectivity in the ratio 95:5. In comparison with the lower stereoselectivities obtained in the reaction of γ-keto sulfoxides bearing p-tolyl or 2,4,6-trimethylphenyl groups, the sterically bulky (2,4,6-triisopropylphenyl)-sulfinyl group is extremely efficient in effecting high 1,4-remote asymmetric induction., application/pdf}, pages = {3143--3148}, title = {1,4-Asymmetric reduction of γ-keto sulfoxides bearing the 2,4,6-triisopropylphenyl group}, volume = {2000}, year = {2000} }