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In comparison with the lower stereoselectivities obtained in the reaction of γ-keto sulfoxides bearing p-tolyl or 2,4,6-trimethylphenyl groups, the sterically bulky (2,4,6-triisopropylphenyl)-sulfinyl group is extremely efficient in effecting high 1,4-remote asymmetric induction.","subitem_description_language":"en","subitem_description_type":"Other"}]},"item_10001_full_name_27":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"8739","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"1000020335087","nameIdentifierScheme":"NRID","nameIdentifierURI":"http://rns.nii.ac.jp/nr/1000020335087"}],"names":[{"name":"中村, 修一"}]},{"nameIdentifiers":[{"nameIdentifier":"10237","nameIdentifierScheme":"WEKO"}],"names":[{"name":"融, 健"}]}]},"item_10001_publisher_29":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Royal Society of Chemistry","subitem_publisher_language":"en"}]},"item_10001_relation_34":{"attribute_name":"item_10001_relation_34","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"10.1039/b004782l"}],"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"http://dx.doi.org/10.1039/b004782l","subitem_relation_type_select":"DOI"}}]},"item_10001_source_id_30":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1472-7781","subitem_source_identifier_type":"ISSN"}]},"item_10001_source_id_32":{"attribute_name":"item_10001_source_id_32","attribute_value_mlt":[{"subitem_source_identifier":"AA11413675","subitem_source_identifier_type":"NCID"}]},"item_10001_version_type_33":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Nakamura, Shuichi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"8739","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"1000020335087","nameIdentifierScheme":"NRID","nameIdentifierURI":"http://rns.nii.ac.jp/nr/1000020335087"}]},{"creatorNames":[{"creatorName":"Kuroyanagi, Masayuki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"15856","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Watanabe, Yoshihiko","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"15857","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Toru, Takeshi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"10237","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-01-24"}],"displaytype":"detail","filename":"JCSP 2000_3143.pdf","filesize":[{"value":"195.7 kB"}],"format":"application/pdf","license_note":"J. 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Soc., Perkin Trans. 1, 2000, 3143-3148 -Reproduced by permission of The Royal Society of Chemistry (RSC)","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"本文_fulltext","url":"https://nitech.repo.nii.ac.jp/record/4865/files/JCSP 2000_3143.pdf"},"version_id":"653ee4b6-16f0-43b1-8bb7-79b8a5b79366"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"item_resource_type","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"1,4-Asymmetric reduction of γ-keto sulfoxides bearing the 2,4,6-triisopropylphenyl group","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"1,4-Asymmetric reduction of γ-keto sulfoxides bearing the 2,4,6-triisopropylphenyl group","subitem_title_language":"en"}]},"item_type_id":"10001","owner":"91","path":["31"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2012-11-06"},"publish_date":"2012-11-06","publish_status":"0","recid":"4865","relation_version_is_last":true,"title":["1,4-Asymmetric reduction of γ-keto sulfoxides bearing the 2,4,6-triisopropylphenyl group"],"weko_creator_id":"91","weko_shared_id":-1},"updated":"2025-03-18T04:41:06.330635+00:00"}