@article{oai:nitech.repo.nii.ac.jp:00005168, author = {Hirashita, Tsunehisa and Kamei, Toshiya and Satake, Makoto and Horie, Tomoaki and Shimizu, Hidetaka and Araki, Shuki}, issue = {21}, journal = {Organic & biomolecular chemistry}, month = {Oct}, note = {Diastereoselective couplings of salicylaldehyde, anisaldehyde and 2-pyridylaldehyde with crotyl- and cinnamyl-indium reagents were studied. The synlanti selectivity was found to depend largely on the ligands on the indium atom of the allylic indium reagents. A syn-selective cinnamylation of salicylaldehyde was realized by the combination of cinnamyl acetate and indium(i) iodide, whereas an anti-selective coupling with salicylaldehyde was achieved by the indium trichloride/aluminium-mediated cinnamylation., application/pdf}, pages = {3799--3803}, title = {Control of diastereoselectivity in the crotylation and cinnamylation of aldehydes by the selection of ligands on allylic indium reagents}, volume = {1}, year = {2003} }