@article{oai:nitech.repo.nii.ac.jp:00005210, author = {Ohkita, Masakazu and Sano, Kieko and Ono, Katsuhiko and Saito, Katsuhiro and Suzuki, Takanori and Tsuji, Takashi}, issue = {17}, journal = {Organic & biomolecular chemistry}, month = {Aug}, note = {Kinetic stabilization of the o-quinoidal 3,4-benzotropone system was investigated. The parent 3,4-benzotropone 1 undergoes rapid [π8 + π10] dimerization in fluid solution even at -78 °C while triptycene-fused derivative 5 having a tert-butyl group at the C(6) position of the tropone moiety was found to be stable indefinitely under similar conditions. The relative importance of the triptycene moiety and the tert-butyl group in 5 for the kinetic stabilization was evaluated., application/pdf}, pages = {2421--2425}, title = {Kinetic stabilization of the o-quinoidal 3,4-benzotropone system}, volume = {2}, year = {2004} }