{"created":"2023-05-15T12:36:06.256272+00:00","id":5291,"links":{},"metadata":{"_buckets":{"deposit":"7b6c03f3-07d6-4733-82c1-b224fe9df3e6"},"_deposit":{"created_by":91,"id":"5291","owners":[91],"pid":{"revision_id":0,"type":"depid","value":"5291"},"status":"published"},"_oai":{"id":"oai:nitech.repo.nii.ac.jp:00005291","sets":["31"]},"author_link":["8722","8644","9783","8722","8644"],"item_10001_biblio_info_28":{"attribute_name":"bibliographic_information","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2006-05","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"5","bibliographicPageEnd":"742","bibliographicPageStart":"737","bibliographicVolumeNumber":"22","bibliographic_titles":[{"bibliographic_title":"Analytical sciences : the international journal of the Japan Society for Analytical Chemistry","bibliographic_titleLang":"en"}]}]},"item_10001_description_36":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"The effect of the surface charge density of heptakis-6-bromo-6-deoxy-β-cyclodextrin (β-CD-BR) bonded silica gels, which was used as the stationary phase of a packed capillary column for HPLC, was investigated concerning the retention behaviors of neutral cresol isomers. On the whole, the retention factors of the cresol isomers increased with an increase in the pH values of the mobile phase, although they were slightly smaller at pH 6.1 than at pH 4.7. An investigation on the retention variation using a van't Hoff plot revealed that the increase in the retention factor (k) at a higher pH region could be mainly attributed to the increase in ΔS, while a partial decrease in k around pH 5 - 6 was caused by a decrease in the -ΔH/T value. On the other hand, a measurement of the electroosmotic flow velocity under various pH of the mobile phase solutions revealed that the retention variations of the neutral cresol isomers were strongly correlated with the surface charge on the packing materials. The positive charge of secondary ammonium functional groups to bind β-CD-BR inhibit the insertion of the cresol isomers into the cavity of β-CD-BR while reducing the retention factor, whereas the negative charge of silanol group enhanced it through a local change in the mobile phase composition.","subitem_description_language":"en","subitem_description_type":"Other"}]},"item_10001_full_name_27":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"8722","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"1000050335080","nameIdentifierScheme":"NRID","nameIdentifierURI":"http://rns.nii.ac.jp/nr/1000050335080"}],"names":[{"name":"北川, 慎也"}]},{"nameIdentifiers":[{"nameIdentifier":"8644","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"1000050176921","nameIdentifierScheme":"NRID","nameIdentifierURI":"http://rns.nii.ac.jp/nr/1000050176921"}],"names":[{"name":"Ohtani, Hajime"}]}]},"item_10001_publisher_29":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"The Japan Society for Analytical Chemistry","subitem_publisher_language":"en"}]},"item_10001_relation_34":{"attribute_name":"item_10001_relation_34","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"10.2116/analsci.22.737"}],"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"http://dx.doi.org/10.2116/analsci.22.737","subitem_relation_type_select":"DOI"}}]},"item_10001_source_id_30":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0910-6340","subitem_source_identifier_type":"ISSN"}]},"item_10001_source_id_32":{"attribute_name":"item_10001_source_id_32","attribute_value_mlt":[{"subitem_source_identifier":"AA10500785","subitem_source_identifier_type":"NCID"}]},"item_10001_version_type_33":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Nakagawa, Hiroyuki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"9783","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Kitagawa, Shinya","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"8722","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"1000050335080","nameIdentifierScheme":"NRID","nameIdentifierURI":"http://rns.nii.ac.jp/nr/1000050335080"}]},{"creatorNames":[{"creatorName":"Ohtani, Hajime","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"8644","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"1000050176921","nameIdentifierScheme":"NRID","nameIdentifierURI":"http://rns.nii.ac.jp/nr/1000050176921"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-01-25"}],"displaytype":"detail","filename":"AS 22_737.pdf","filesize":[{"value":"122.6 kB"}],"format":"application/pdf","license_note":"2006 cThe Japan Society for Analytical Chemistry","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"本文_fulltext","url":"https://nitech.repo.nii.ac.jp/record/5291/files/AS 22_737.pdf"},"version_id":"96a7e0cb-28a6-449e-9525-7c6394289eb0"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"item_resource_type","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Effect of the Net Surface Charge Density of Heptakis-6-bromo-6-deoxy-β-cyclodextrin Bonded Silica Gels on the Retention Behaviors of Neutral Cresol Isomers in HPLC","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Effect of the Net Surface Charge Density of Heptakis-6-bromo-6-deoxy-β-cyclodextrin Bonded Silica Gels on the Retention Behaviors of Neutral Cresol Isomers in HPLC","subitem_title_language":"en"}]},"item_type_id":"10001","owner":"91","path":["31"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2012-11-06"},"publish_date":"2012-11-06","publish_status":"0","recid":"5291","relation_version_is_last":true,"title":["Effect of the Net Surface Charge Density of Heptakis-6-bromo-6-deoxy-β-cyclodextrin Bonded Silica Gels on the Retention Behaviors of Neutral Cresol Isomers in HPLC"],"weko_creator_id":"91","weko_shared_id":-1},"updated":"2025-03-19T07:02:03.683069+00:00"}