{"created":"2023-05-15T12:36:11.406238+00:00","id":5413,"links":{},"metadata":{"_buckets":{"deposit":"38f6552a-781b-4d6d-b83e-c5b7475b1e60"},"_deposit":{"created_by":91,"id":"5413","owners":[91],"pid":{"revision_id":0,"type":"depid","value":"5413"},"status":"published"},"_oai":{"id":"oai:nitech.repo.nii.ac.jp:00005413","sets":["31"]},"author_link":["8710","8811","8710","18875","18876","18877","18878","9598","8811"],"item_10001_biblio_info_28":{"attribute_name":"bibliographic_information","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2008-12","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"12","bibliographicPageEnd":"1580","bibliographicPageStart":"1575","bibliographicVolumeNumber":"24","bibliographic_titles":[{"bibliographic_title":"Analytical sciences : the international journal of the Japan Society for Analytical Chemistry","bibliographic_titleLang":"en"}]}]},"item_10001_description_36":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"The redox potentials of cobalt and iron complexes with ten pyridylazo compounds, E0ML2 (ML2+/0; M: CoIII/II, FeIII/II; L-: pyridylazo compounds), have been determined in order to explore the difference in their reversed-phase HPLC behavior. The redox potentials of Co complexes were in the range of -0.62 - 0.03 V, while those of Fe complexes were -0.06 - 0.59 V relative to 0.20 V for ferricinium/ferrocene. The redox potentials of both the Co and Fe complexes were linearly correlated to the basicities of the ligands. The correlation was quantitatively explained by a difference in dependence of the stabilities of MIII and MII complexes on the ligand basicities. The complex of [CoIIIL2]+ or [FeIIL2] with any compound injected in the reversed-phase HPLC system was detected without any change in the composition. When [CoIIL2] was injected, only those complexes having the highest potentials of E0CoL2 ? 0.0 V were detected as [CoIIL2], while other complexes having lower potentials gave a peak of [CoIIIL2]+. When [FeIIIL2]+ was injected, only complexes having the lowest potentials of E0FeL2 ? 0.0 V were detected as [FeIIIL2]+, while others having higher potentials gave a peak of [FeIIL2].","subitem_description_language":"en","subitem_description_type":"Other"}]},"item_10001_full_name_27":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"8710","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"1000060270998","nameIdentifierScheme":"NRID","nameIdentifierURI":"http://rns.nii.ac.jp/nr/1000060270998"}],"names":[{"name":"安井, 孝志"}]},{"familyNames":[{"familyName":"Yuchi","familyNameLang":"en"},{"familyName":"湯地","familyNameLang":"ja"},{"familyName":"ユチ","familyNameLang":"ja-Kana"}],"givenNames":[{"givenName":"Akio","givenNameLang":"en"},{"givenName":"昭夫","givenNameLang":"ja"},{"givenName":"アキオ","givenNameLang":"ja-Kana"}],"nameIdentifiers":[{"nameIdentifier":"8811","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Yuchi, Akio","nameLang":"en"},{"name":"湯地, 昭夫","nameLang":"ja"},{"name":"ユチ, アキオ","nameLang":"ja-Kana"}]}]},"item_10001_publisher_29":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"The Japan Society for Analytical Chemistry","subitem_publisher_language":"en"}]},"item_10001_relation_34":{"attribute_name":"item_10001_relation_34","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"10.2116/analsci.24.1575"}],"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"http://dx.doi.org/10.2116/analsci.24.1575","subitem_relation_type_select":"DOI"}}]},"item_10001_source_id_30":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0910-6340","subitem_source_identifier_type":"ISSN"}]},"item_10001_source_id_32":{"attribute_name":"item_10001_source_id_32","attribute_value_mlt":[{"subitem_source_identifier":"AA10500785","subitem_source_identifier_type":"NCID"}]},"item_10001_version_type_33":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Yasui, 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Hiromichi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"9598","nameIdentifierScheme":"WEKO"}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifierScheme":"ISNI","affiliationNameIdentifierURI":"http://www.isni.org/isni/"}],"affiliationNames":[{"affiliationNameLang":"ja"}]}],"creatorNames":[{"creatorName":"Yuchi, Akio","creatorNameLang":"en"},{"creatorName":"湯地, 昭夫","creatorNameLang":"ja"},{"creatorName":"ユチ, アキオ","creatorNameLang":"ja-Kana"}],"familyNames":[{"familyName":"Yuchi","familyNameLang":"en"},{"familyName":"湯地","familyNameLang":"ja"},{"familyName":"ユチ","familyNameLang":"ja-Kana"}],"givenNames":[{"givenName":"Akio","givenNameLang":"en"},{"givenName":"昭夫","givenNameLang":"ja"},{"givenName":"アキオ","givenNameLang":"ja-Kana"}],"nameIdentifiers":[{"nameIdentifier":"8811","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-01-25"}],"displaytype":"detail","filename":"AS 24_1575.pdf","filesize":[{"value":"711.8 kB"}],"format":"application/pdf","license_note":"2008 c The Japan Society for Analytical Chemistry","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"本文_fulltext","url":"https://nitech.repo.nii.ac.jp/record/5413/files/AS 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Compounds"],"weko_creator_id":"91","weko_shared_id":-1},"updated":"2025-03-21T03:00:15.781809+00:00"}