{"created":"2023-05-15T12:36:11.613968+00:00","id":5418,"links":{},"metadata":{"_buckets":{"deposit":"a001fea7-833e-4cf6-8c15-57810055bb9f"},"_deposit":{"created_by":91,"id":"5418","owners":[91],"pid":{"revision_id":0,"type":"depid","value":"5418"},"status":"published"},"_oai":{"id":"oai:nitech.repo.nii.ac.jp:00005418","sets":["31"]},"author_link":["8741","8750","18910","7702","18912","8741","18914","8750"],"item_10001_biblio_info_28":{"attribute_name":"bibliographic_information","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2009-01-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1361","bibliographicPageEnd":"26","bibliographicPageStart":"22","bibliographicVolumeNumber":"117","bibliographic_titles":[{"bibliographic_title":"Journal of the Ceramic Society of Japan","bibliographic_titleLang":"en"}]}]},"item_10001_description_36":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"Two types of new quaternary carbide solid solutions, (ZrC)_2Al_3[Al_<1-x>Ge_x]C_3 (x=0.07) and (ZrC)_3Al_3[Al_<1-y>Ge_y]C_3 (y=0.04), have been synthesized and characterized using a laboratory X-ray powder diffractometer (XRPD) and a transmission electron microscope (TEM) equipped with an energy dispersive X-ray analyzer (EDX). With the former carbide, the layered structure was imaged by TEM and the solubility of Ge in the crystal was confirmed by EDX. The crystal structures of both carbides were refined by the Rietveld analysis of the XRPD data. These carbides have been found to form a homologous series with the general formula (ZrC)_mAl_3[Al_<1-z>Ge_z]C_3 (0?z?0.07), where m=2 and 3. The crystal structures can be regarded as intergrowth structures, consisting of the NaCl-type [Zr_mC_<m+1>] slabs separated by the Al_4C_3-type [Al_<4-Z>Ge_zC_4] layers.","subitem_description_language":"en","subitem_description_type":"Other"}]},"item_10001_full_name_27":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"8741","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"1000010242900","nameIdentifierScheme":"NRID","nameIdentifierURI":"http://rns.nii.ac.jp/nr/1000010242900"}],"names":[{"name":"橋本, 忍"}]},{"nameIdentifiers":[{"nameIdentifier":"8750","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"1000090189944","nameIdentifierScheme":"NRID","nameIdentifierURI":"http://rns.nii.ac.jp/nr/1000090189944"}],"names":[{"name":"福田, 功一郎"}]}]},"item_10001_publisher_29":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"The Ceramic Society of Japan","subitem_publisher_language":"en"}]},"item_10001_relation_34":{"attribute_name":"item_10001_relation_34","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"10.2109/jcersj2.117.22"}],"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"http://dx.doi.org/10.2109/jcersj2.117.22","subitem_relation_type_select":"DOI"}}]},"item_10001_source_id_30":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1882-0743","subitem_source_identifier_type":"ISSN"}]},"item_10001_source_id_32":{"attribute_name":"item_10001_source_id_32","attribute_value_mlt":[{"subitem_source_identifier":"AA12229489","subitem_source_identifier_type":"NCID"}]},"item_10001_version_type_33":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Sugiura, Keita","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"18910","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Iwata, Tomoyuki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"7702","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Sunada, Naohiro","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"18912","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Hashimoto, Shinobu","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"8741","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"1000010242900","nameIdentifierScheme":"NRID","nameIdentifierURI":"http://rns.nii.ac.jp/nr/1000010242900"}]},{"creatorNames":[{"creatorName":"Nakano, Hiromi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"18914","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Fukuda, Koichiro","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"8750","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"1000090189944","nameIdentifierScheme":"NRID","nameIdentifierURI":"http://rns.nii.ac.jp/nr/1000090189944"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-01-25"}],"displaytype":"detail","filename":"JCSJ 117_22.pdf","filesize":[{"value":"813.2 kB"}],"format":"application/pdf","license_note":"(c) 2009 The Ceramic Society of Japan","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"本文_fulltext","url":"https://nitech.repo.nii.ac.jp/record/5418/files/JCSJ 117_22.pdf"},"version_id":"e5944813-8363-4ece-be50-f729389502d7"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"item_resource_type","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Syntheses and crystal structures of Ge-bearing layered carbides Zr_2Al_4C_5 and Zr_3Al_4C_6","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Syntheses and crystal structures of Ge-bearing layered carbides Zr_2Al_4C_5 and Zr_3Al_4C_6","subitem_title_language":"en"}]},"item_type_id":"10001","owner":"91","path":["31"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2012-11-06"},"publish_date":"2012-11-06","publish_status":"0","recid":"5418","relation_version_is_last":true,"title":["Syntheses and crystal structures of Ge-bearing layered carbides Zr_2Al_4C_5 and Zr_3Al_4C_6"],"weko_creator_id":"91","weko_shared_id":-1},"updated":"2025-03-21T03:00:29.846003+00:00"}