{"created":"2023-05-15T12:36:17.198621+00:00","id":5527,"links":{},"metadata":{"_buckets":{"deposit":"0dba095a-b6df-44d6-b26c-229e6cfd88aa"},"_deposit":{"created_by":3,"id":"5527","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"5527"},"status":"published"},"_oai":{"id":"oai:nitech.repo.nii.ac.jp:00005527","sets":["31"]},"author_link":["19543","8802","19545","19546","19544","19542"],"item_10001_alternative_title_24":{"attribute_name":"その他（別言語等）のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"ポリスチレン　スルホンサン　オ　テキテイザイ　トシタ　コロイド　テキテイ　－　トルイジン　ブルー　ノ　メタマクロマジー　ト　デンイサ　コロイド　テキテイ　－"}]},"item_10001_biblio_info_28":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2011-05-05","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"5","bibliographicPageEnd":"425","bibliographicPageStart":"419","bibliographicVolumeNumber":"60","bibliographic_titles":[{"bibliographic_title":"分析化学 = Japan analyst"}]}]},"item_10001_description_36":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"ポリビニル硫酸（PVS）とトルイジンブルー（TB）とのメタクロマジーとポリスチレンスルホン酸（PSS）とTBとのメタクロマジーについて，マイクロプレートを用いた目視法と紫外可視分光法で調べた．また，PSS-TBの会合系を軽水1H-NMR法によって調べた．その結果，TBを指示薬とする目視コロイド滴定においてPSSのメタクロマジーが終点で不明瞭である理由は，PSSのスチレン基に，芳香環を持つTBがπ－π相互作用でスタッキングするために，TBがPSSにrandom型の会合を起しやすいことが原因であると解釈された．さらに，界面活性剤電極を用いてTBを指示薬とするPSSの電位差コロイド滴定を行った．PSSを用いる電位差滴定によれば，TBを用いても化学量論的な終点が得られた．PSSとPVSをそれぞれ滴定剤とするコロイド滴定において，塩化テトラデシルトリメチルベンジルアンモニウム（Zeph）を標準物質とすると，高分子量のポリ塩化ジアリルジメチルアンモニウム（PDADMAC）に対するそれぞれの滴定値は2％ 以内の相対差で一致した．","subitem_description_type":"Other"}]},"item_10001_description_38":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_10001_full_name_27":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{}],"names":[{"name":"Yoshino, Akihiro"}]}]},"item_10001_publisher_29":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"日本分析化学会"}]},"item_10001_relation_34":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"10.2116/bunsekikagaku.60.419"}],"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"http://dx.doi.org/10.2116/bunsekikagaku.60.419","subitem_relation_type_select":"DOI"}}]},"item_10001_source_id_30":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"05251931","subitem_source_identifier_type":"ISSN"}]},"item_10001_source_id_32":{"attribute_name":"書誌レコードID（NCID）","attribute_value_mlt":[{"subitem_source_identifier":"AN00222633","subitem_source_identifier_type":"NCID"}]},"item_10001_version_type_33":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"服部, 敏明"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"内藤, 洋子"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"伊藤, 義徳"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"加藤, 亮"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"平田, 幸夫"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"吉野, 明広"},{"creatorName":"ヨシノ, アキヒロ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-01-26"}],"displaytype":"detail","filename":"YoshinoAkihiro_2011_JA.pdf","filesize":[{"value":"8.0 MB"}],"format":"application/pdf","license_note":"Copyright(2011) The Japan Society for Analytical Chemistry","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"本文_fulltext","url":"https://nitech.repo.nii.ac.jp/record/5527/files/YoshinoAkihiro_2011_JA.pdf"},"version_id":"99d164ce-9ac8-40d7-ad22-fded968203c8"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"ポリスチレンスルホン酸を滴定剤としたコロイド滴定　－トルイジンブルーのメタマクロマジーと電位差コロイド滴定－","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"ポリスチレンスルホン酸を滴定剤としたコロイド滴定　－トルイジンブルーのメタマクロマジーと電位差コロイド滴定－"}]},"item_type_id":"10001","owner":"3","path":["31"],"pubdate":{"attribute_name":"公開日","attribute_value":"2013-07-01"},"publish_date":"2013-07-01","publish_status":"0","recid":"5527","relation_version_is_last":true,"title":["ポリスチレンスルホン酸を滴定剤としたコロイド滴定　－トルイジンブルーのメタマクロマジーと電位差コロイド滴定－"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2023-05-15T14:21:25.614295+00:00"}