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Synthesis and molecular structure of a lithium complex of the phthalocyanine radical
https://nitech.repo.nii.ac.jp/records/3845
https://nitech.repo.nii.ac.jp/records/3845188be502-282b-4362-83a3-01c19f37631a
名前 / ファイル | ライセンス | アクション |
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本文_fulltext (191.3 kB)
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J. CHEM. SOC., CHEM. COMMUN., 1986, 962-963 - Reproduced by permission of The Royal Society of Chemistry (RSC)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2012-11-06 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Synthesis and molecular structure of a lithium complex of the phthalocyanine radical | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Sugimoto, Hiroshi
× Sugimoto, Hiroshi× Mori, Masayasu× Masuda, Hideki× Taga, Toru |
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著者別名 | ||||||
姓名 | 増田, 秀樹 | |||||
書誌情報 |
Journal of the Chemical Society. Chemical communications 巻 1986, 号 12, p. 962-963, 発行日 1986-01-01 |
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出版者 | ||||||
出版者 | Royal Society of Chemistry | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 00224936 | |||||
書誌レコードID(NCID) | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA00695098 | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
DOI | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | DOI | |||||
関連識別子 | http://dx.doi.org/10.1039/C39860000962 | |||||
関連名称 | 10.1039/C39860000962 | |||||
内容記述 | ||||||
内容記述タイプ | Other | |||||
内容記述 | Controlled potential electrolysis of the dilithium salt of phthalocyanine, Li2(pc2-), at 0.15 V vs. saturated calomel electrode in acetonitrile gave a lithium complex of the phthalocyanine radical, the crystal structure of which shows that it contains a unit cell with four nearly planar Li(pc・-) molecules of S4 symmetry, stacked metal-over-metal with an Li-Li spacing of 3.245(2)A, and staggered by 38.7(3)°; its effective magnetic moment decreased from the room temperature value of 1.3 μB to 1.0 μB at 150 K, but upon further cooling it increased to approach the free-spin value. | |||||
フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf |