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ゲルマニウム(IV)錯体のアニオノフォアとしての特性
https://nitech.repo.nii.ac.jp/records/3559
https://nitech.repo.nii.ac.jp/records/35599243eccd-7e6d-468f-b72e-b2cb5fa8a814
名前 / ファイル | ライセンス | アクション |
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本文_fulltext (287.2 kB)
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c 2004 The Japan Society for Analytical Chemistry
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2012-11-06 | |||||
タイトル | ||||||
タイトル | ゲルマニウム(IV)錯体のアニオノフォアとしての特性 | |||||
言語 | ||||||
言語 | jpn | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
その他(別言語等)のタイトル | ||||||
その他のタイトル | Performance of germanium (IV) complexes as anionophore | |||||
著者 |
宇野, 弘重
× 宇野, 弘重× 鈴木, 崇嗣× 後藤, 康正× 伊藤, 慎祐× 安井, 孝志× 湯地, 昭夫 |
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著者別名 | ||||||
姓名 | Yasui, Takashi | |||||
著者別名 | ||||||
姓名 | Yuchi, Akio | |||||
書誌情報 |
分析化学 = Japan analyst 巻 53, 号 9, p. 1035-1038, 発行日 2004 |
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出版者 | ||||||
出版者 | 日本分析化学会 | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 05251931 | |||||
書誌レコードID(NCID) | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AN00222633 | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
DOI | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | DOI | |||||
関連識別子 | http://dx.doi.org/10.2116/bunsekikagaku.53.1035 | |||||
関連名称 | 10.2116/bunsekikagaku.53.1035 | |||||
内容記述 | ||||||
内容記述タイプ | Other | |||||
内容記述 | A few germanium(IV) complexes were prepared and examined for the anionophore. A nitrilotriphenolato complex ([Ge2(ntp)2O]) with three coordinating phenolates around Ge(IV) showed a sub-Nernstian response (40 mV/decade) to fluoride in the range of 10-3?10-1 mol dm-3 as a carrier of ion-selective electrodes(ISEs). The dynamic range was extended to 10-4?10-1 mol dm-3 in the presence of cationic additives. Spectroscopic studies on the reaction of this complex with anions in dimethyl sulfoxide demonstrated the reaction stoichiometry of Ge(IV) : A- = 1 : 1 and the thermodynamic stability order of F- > CH3COO- > H2PO4-. The reaction selectivity agreed with that of potentiometry with ISEs. A bis(catecholato) complex with four phenolates showed no response to anions, and a bis(aminophenolato) complex with two phenolates was not stable enough in the reaction with anions. | |||||
フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf |