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Crystal structures and single-crystal electron spin resonance spectra of π-π Type molecular complexes of bis(1-methyliminomethyl-2-naphtholato)copper(II)
https://nitech.repo.nii.ac.jp/records/4258
https://nitech.repo.nii.ac.jp/records/4258956fb445-9aa5-4873-8927-2e94abb0a9ef
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
本文_fulltext (645.1 kB)
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J. CHEM. SOC. DALTON TRANS. 1994, 2065-Reproduced by permission of The Royal Society of Chemistry (RSC)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||||||||||||
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| 公開日 | 2012-11-07 | |||||||||||||||
| タイトル | ||||||||||||||||
| タイトル | Crystal structures and single-crystal electron spin resonance spectra of π-π Type molecular complexes of bis(1-methyliminomethyl-2-naphtholato)copper(II) | |||||||||||||||
| 言語 | en | |||||||||||||||
| 言語 | ||||||||||||||||
| 言語 | eng | |||||||||||||||
| 資源タイプ | ||||||||||||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||||||||
| 資源タイプ | journal article | |||||||||||||||
| 著者 |
Shiotsuka, Michito
× Shiotsuka, Michito
× Okaue, Yoshihiro
× Matsumoto, Naohide
× Okawa, Hisashi
× Isobe, Toshiyuki
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| 著者別名 | ||||||||||||||||
| 姓名 | 塩塚, 理仁 | |||||||||||||||
| 書誌情報 |
en : Journal of the Chemical Society. Dalton transactions 巻 1994, 号 14, p. 2065-2070, 発行日 1994-01-01 |
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| 出版者 | ||||||||||||||||
| 出版者 | Royal Society of Chemistry | |||||||||||||||
| 言語 | en | |||||||||||||||
| ISSN | ||||||||||||||||
| 収録物識別子タイプ | ISSN | |||||||||||||||
| 収録物識別子 | 0300-9246 | |||||||||||||||
| item_10001_source_id_32 | ||||||||||||||||
| 収録物識別子タイプ | NCID | |||||||||||||||
| 収録物識別子 | AA00695101 | |||||||||||||||
| 出版タイプ | ||||||||||||||||
| 出版タイプ | VoR | |||||||||||||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||||||||||||
| item_10001_relation_34 | ||||||||||||||||
| 関連タイプ | isIdenticalTo | |||||||||||||||
| 識別子タイプ | DOI | |||||||||||||||
| 関連識別子 | http://dx.doi.org/10.1039/DT9940002065 | |||||||||||||||
| 関連名称 | 10.1039/DT9940002065 | |||||||||||||||
| 内容記述 | ||||||||||||||||
| 内容記述タイプ | Other | |||||||||||||||
| 内容記述 | The donor-acceptor molecular complexes of bis(1-methyliminomethyl-2-naphtholato)copper(II)[CuL2] with 7,7,8,8-tetracyanoquinodimethane (tcnq), tetrachloro-1,4-benzoquinone (tcbq) and 1,3,5-trinitrobenzene (tnb), as well as the parent complex have been subjected to single-crystal X-ray diffraction analysis. The molecular complexes [CuL2]・2tcnq and [CuL2]・2tnb crystallize in the triclinic space group P and [CuL2]・2tcbq crystallizes in the monoclinic space group P21/n, the copper atoms of all complexes being positioned at an inversion centre. The molecular complexes showed a typical π-π type structure consisting of alternately stacked π-electron donor (naphthalene moiety of copper complex) and π-electron acceptor (tcnq, tcbq and tnb) along the c axis (needle axis). The ESR spectrum for a copper(II) doped sample of diamagnetic [NiL2]・2tnb showed simple copper quartet lines due to I=. The X-ray analyses indicated that the donor-acceptor interaction operating along the c axis gives a one-dimensional structure consisting of alternately stacked donor and acceptor molecules, but no distinct two-dimensional interaction. | |||||||||||||||
| 言語 | en | |||||||||||||||
