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Bonding interaction between Group 10 and 11 metals. Synthesis, structure and properties of [M3(S2CNR2)6M′2]2+(M = Pt or Pd; M′= Ag or Cu; R = Et, Pri, Prn, Bun or C6H11)
https://nitech.repo.nii.ac.jp/records/4266
https://nitech.repo.nii.ac.jp/records/4266ed35a807-9c40-4ae1-ba17-d9db4c8ca555
名前 / ファイル | ライセンス | アクション |
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本文_fulltext (1.8 MB)
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J. CHEM. SOC. DALTON TRANS. 1994, 3621-3635 -Reproduced by permission of The Royal Society of Chemistry (RSC)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2012-11-06 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Bonding interaction between Group 10 and 11 metals. Synthesis, structure and properties of [M3(S2CNR2)6M′2]2+(M = Pt or Pd; M′= Ag or Cu; R = Et, Pri, Prn, Bun or C6H11) | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Ebihara, Masahiro
× Ebihara, Masahiro× Tokoro, Kenji× Maeda, Minobu× Ogami, Masaki× Imaeda, Kaori× Sakurai, Kenji× Masuda, Hideki× Kawamura, Takashi |
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著者別名 | ||||||
姓名 | 増田, 秀樹 | |||||
書誌情報 |
Journal of the Chemical Society. Dalton transactions 巻 1994, 号 24, p. 3621-3635, 発行日 1994-01-01 |
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出版者 | ||||||
出版者 | Royal Society of Chemistry | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 03009246 | |||||
書誌レコードID(NCID) | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA00695101 | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
DOI | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | DOI | |||||
関連識別子 | http://dx.doi.org/10.1039/DT9940003621 | |||||
関連名称 | 10.1039/DT9940003621 | |||||
内容記述 | ||||||
内容記述タイプ | Other | |||||
内容記述 | The mixed-metal complexes [M3(S2CNR2)6M′ 2]2+ (M = Pt or Pd; M′ = Ag or Cu; R = Et, Pri, Prn, Bun or C6H11) have been prepared quantitatively upon mixing stoichiometric amounts of [M(S2CNR2)2 and Ag+ or [Cu(MeCN)4]+ in dichloromethane. The structures of nine of them have been determined and are classified into three types: one polymer and two discrete ion structures. Comparison of the structures indicates the existence of a bonding interaction between M and M′ that is greater for Pt than Pd and for Ag than Cu. The strong bonding interaction between the Pt and Ag atoms is also supported by the 195Pt-107,109Ag coupling constant of 194 Hz for [Pt3(S2CNBun2)6Ag 2]2+. | |||||
フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf |