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  1. 研究論文

Structural Change in Phosphorus-Bearing Dicalcium Silicates

https://nitech.repo.nii.ac.jp/records/4472
https://nitech.repo.nii.ac.jp/records/4472
1c54c459-561d-459e-a6e0-b11175af9c12
名前 / ファイル ライセンス アクション
JCSJ 本文_fulltext (1.9 MB)
(c) 1997 The Ceramic Society of Japan
Item type 学術雑誌論文 / Journal Article(1)
公開日 2012-11-06
タイトル
タイトル Structural Change in Phosphorus-Bearing Dicalcium Silicates
言語 en
言語
言語 eng
資源タイプ
資源タイプ識別子 http://purl.org/coar/resource_type/c_6501
資源タイプ journal article
その他(別言語等)のタイトル
その他のタイトル リンを固溶したケイ酸カルシウムの構造変化
言語 ja
著者 Fukuda, Koichiro

× Fukuda, Koichiro

en Fukuda, Koichiro

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Maki, Iwao

× Maki, Iwao

en Maki, Iwao

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Ito, Suketoshi

× Ito, Suketoshi

en Ito, Suketoshi

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Miyake, Takayuki

× Miyake, Takayuki

en Miyake, Takayuki

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著者別名
姓名 福田, 功一郎
bibliographic_information en : Journal of the Ceramic Society of Japan

巻 105, 号 1218, p. 117-121, 発行日 1997-02-01
出版者
出版者 The Ceramic Society of Japan
言語 en
ISSN
収録物識別子タイプ ISSN
収録物識別子 0914-5400
item_10001_source_id_32
収録物識別子タイプ NCID
収録物識別子 AN10040326
出版タイプ
出版タイプ VoR
出版タイプResource http://purl.org/coar/version/c_970fb48d4fbd8a85
内容記述
内容記述タイプ Other
内容記述 Structures of (Ca_<2-x/2>□_<x/2>) (Si_<1-x>P_x)O_4 crystals were examined as a function of x ranging from 0.03 to 0.40. All of the samples were heated at the stable temperature region of the α-phase and then quenched in water. The phase constitution at ambient temperature was classified into three categories according to the fraction of the α-to-α´_H transition. When the transition was completed as in the crystals with x?0.100, the β- and α´_L-phases were obtained, the relative amounts of which were determined by the start and finish temperatures of the α´_L-to-β martensitic transformation. With 0.125?x?0.150, the α-to-α´_H transition was incomplete. During further cooling, the product α´_H-Phase was inverted to the α´_L-Phase, and the residual α-phase was inverted to the incommensurate phase successively. Because the start temperature of the α´_L-to-β transformation was lower than ambient temperature, the α´_L-Phase was stabilized. With x?0.175, all of the crystals were free from the α-to-α´_H transition. The crystals with 0.175?x?0.225 were made up exclusively of the incommensurate phase. A good correlation existed between the modulation wavelength (=N) and the P/ (Si+P) ratio (=x) as N=4.134-1.56x (0.175?x?0.250). With 0.275?x?0.300, the crystals were isostructural with α-Ca_2SiO_4. The hexagonal phase with 0.350?x?0.400, probably a transition product from the α-phase, showed two-dimensional modulations along the α-axis with N=2 and along the c-axis with N=3.
言語 en
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