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Structural Change in Phosphorus-Bearing Dicalcium Silicates
https://nitech.repo.nii.ac.jp/records/4472
https://nitech.repo.nii.ac.jp/records/44721c54c459-561d-459e-a6e0-b11175af9c12
名前 / ファイル | ライセンス | アクション |
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(c) 1997 The Ceramic Society of Japan
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Item type | 学術雑誌論文 / Journal Article(1) | |||||||||||||
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公開日 | 2012-11-06 | |||||||||||||
タイトル | ||||||||||||||
タイトル | Structural Change in Phosphorus-Bearing Dicalcium Silicates | |||||||||||||
言語 | en | |||||||||||||
言語 | ||||||||||||||
言語 | eng | |||||||||||||
資源タイプ | ||||||||||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||||||
資源タイプ | journal article | |||||||||||||
その他(別言語等)のタイトル | ||||||||||||||
その他のタイトル | リンを固溶したケイ酸カルシウムの構造変化 | |||||||||||||
言語 | ja | |||||||||||||
著者 |
Fukuda, Koichiro
× Fukuda, Koichiro
× Maki, Iwao
× Ito, Suketoshi
× Miyake, Takayuki
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著者別名 | ||||||||||||||
姓名 | 福田, 功一郎 | |||||||||||||
bibliographic_information |
en : Journal of the Ceramic Society of Japan 巻 105, 号 1218, p. 117-121, 発行日 1997-02-01 |
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出版者 | ||||||||||||||
出版者 | The Ceramic Society of Japan | |||||||||||||
言語 | en | |||||||||||||
ISSN | ||||||||||||||
収録物識別子タイプ | ISSN | |||||||||||||
収録物識別子 | 0914-5400 | |||||||||||||
item_10001_source_id_32 | ||||||||||||||
収録物識別子タイプ | NCID | |||||||||||||
収録物識別子 | AN10040326 | |||||||||||||
出版タイプ | ||||||||||||||
出版タイプ | VoR | |||||||||||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||||||||||
内容記述 | ||||||||||||||
内容記述タイプ | Other | |||||||||||||
内容記述 | Structures of (Ca_<2-x/2>□_<x/2>) (Si_<1-x>P_x)O_4 crystals were examined as a function of x ranging from 0.03 to 0.40. All of the samples were heated at the stable temperature region of the α-phase and then quenched in water. The phase constitution at ambient temperature was classified into three categories according to the fraction of the α-to-α´_H transition. When the transition was completed as in the crystals with x?0.100, the β- and α´_L-phases were obtained, the relative amounts of which were determined by the start and finish temperatures of the α´_L-to-β martensitic transformation. With 0.125?x?0.150, the α-to-α´_H transition was incomplete. During further cooling, the product α´_H-Phase was inverted to the α´_L-Phase, and the residual α-phase was inverted to the incommensurate phase successively. Because the start temperature of the α´_L-to-β transformation was lower than ambient temperature, the α´_L-Phase was stabilized. With x?0.175, all of the crystals were free from the α-to-α´_H transition. The crystals with 0.175?x?0.225 were made up exclusively of the incommensurate phase. A good correlation existed between the modulation wavelength (=N) and the P/ (Si+P) ratio (=x) as N=4.134-1.56x (0.175?x?0.250). With 0.275?x?0.300, the crystals were isostructural with α-Ca_2SiO_4. The hexagonal phase with 0.350?x?0.400, probably a transition product from the α-phase, showed two-dimensional modulations along the α-axis with N=2 and along the c-axis with N=3. | |||||||||||||
言語 | en |