WEKO3
アイテム
{"_buckets": {"deposit": "38f6552a-781b-4d6d-b83e-c5b7475b1e60"}, "_deposit": {"created_by": 3, "id": "5413", "owners": [3], "pid": {"revision_id": 0, "type": "depid", "value": "5413"}, "status": "published"}, "_oai": {"id": "oai:nitech.repo.nii.ac.jp:00005413", "sets": ["31"]}, "author_link": ["18876", "18875", "9598", "8710", "18877", "8811", "18878"], "item_10001_biblio_info_28": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2008-12", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "12", "bibliographicPageEnd": "1580", "bibliographicPageStart": "1575", "bibliographicVolumeNumber": "24", "bibliographic_titles": [{"bibliographic_title": "Analytical sciences : the international journal of the Japan Society for Analytical Chemistry"}]}]}, "item_10001_description_36": {"attribute_name": "内容記述", "attribute_value_mlt": [{"subitem_description": "The redox potentials of cobalt and iron complexes with ten pyridylazo compounds, E0ML2 (ML2+/0; M: CoIII/II, FeIII/II; L-: pyridylazo compounds), have been determined in order to explore the difference in their reversed-phase HPLC behavior. The redox potentials of Co complexes were in the range of -0.62 - 0.03 V, while those of Fe complexes were -0.06 - 0.59 V relative to 0.20 V for ferricinium/ferrocene. The redox potentials of both the Co and Fe complexes were linearly correlated to the basicities of the ligands. The correlation was quantitatively explained by a difference in dependence of the stabilities of MIII and MII complexes on the ligand basicities. The complex of [CoIIIL2]+ or [FeIIL2] with any compound injected in the reversed-phase HPLC system was detected without any change in the composition. When [CoIIL2] was injected, only those complexes having the highest potentials of E0CoL2 ? 0.0 V were detected as [CoIIL2], while other complexes having lower potentials gave a peak of [CoIIIL2]+. When [FeIIIL2]+ was injected, only complexes having the lowest potentials of E0FeL2 ? 0.0 V were detected as [FeIIIL2]+, while others having higher potentials gave a peak of [FeIIL2].", "subitem_description_type": "Other"}]}, "item_10001_description_38": {"attribute_name": "フォーマット", "attribute_value_mlt": [{"subitem_description": "application/pdf", "subitem_description_type": "Other"}]}, "item_10001_full_name_27": {"attribute_name": "著者別名", "attribute_value_mlt": [{"nameIdentifiers": [{"nameIdentifier": "8710", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "1000060270998", "nameIdentifierScheme": "NRID", "nameIdentifierURI": "http://rns.nii.ac.jp/nr/1000060270998"}], "names": [{"name": "安井, 孝志"}]}, {"nameIdentifiers": [{"nameIdentifier": "8811", "nameIdentifierScheme": "WEKO"}], "names": [{"name": "湯地, 昭夫"}]}]}, "item_10001_publisher_29": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "The Japan Society for Analytical Chemistry"}]}, "item_10001_relation_34": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_name": [{"subitem_relation_name_text": "10.2116/analsci.24.1575"}], "subitem_relation_type": "isIdenticalTo", "subitem_relation_type_id": {"subitem_relation_type_id_text": "http://dx.doi.org/10.2116/analsci.24.1575", "subitem_relation_type_select": "DOI"}}]}, "item_10001_source_id_30": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "09106340", "subitem_source_identifier_type": "ISSN"}]}, "item_10001_source_id_32": {"attribute_name": "書誌レコードID(NCID)", "attribute_value_mlt": [{"subitem_source_identifier": "AA10500785", "subitem_source_identifier_type": "NCID"}]}, "item_10001_version_type_33": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_970fb48d4fbd8a85", "subitem_version_type": "VoR"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Yasui, Takashi", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "8710", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "1000060270998", "nameIdentifierScheme": "NRID", "nameIdentifierURI": "http://rns.nii.ac.jp/nr/1000060270998"}]}, {"creatorNames": [{"creatorName": "Nunome, Yoko", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "18875", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Onishi, Takashi", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "18876", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Yamaguchi, Masayo", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "18877", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Tamamura, Saki", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "18878", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Yamada, Hiromichi", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "9598", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Yuchi, Akio", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "8811", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2017-01-25"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "AS 24_1575.pdf", "filesize": [{"value": "711.8 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensefree": "2008 c The Japan Society for Analytical Chemistry", "licensetype": "license_free", "mimetype": "application/pdf", "size": 711800.0, "url": {"label": "本文_fulltext", "url": "https://nitech.repo.nii.ac.jp/record/5413/files/AS 24_1575.pdf"}, "version_id": "b9f56971-416e-4512-b7cd-69f9fbb3d700"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Redox Potentials and HPLC Behavior of Cobalt and Iron Complexes with Pyridylazo Compounds", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Redox Potentials and HPLC Behavior of Cobalt and Iron Complexes with Pyridylazo Compounds", "subitem_title_language": "en"}]}, "item_type_id": "10001", "owner": "3", "path": ["31"], "permalink_uri": "https://nitech.repo.nii.ac.jp/records/5413", "pubdate": {"attribute_name": "公開日", "attribute_value": "2012-11-06"}, "publish_date": "2012-11-06", "publish_status": "0", "recid": "5413", "relation": {}, "relation_version_is_last": true, "title": ["Redox Potentials and HPLC Behavior of Cobalt and Iron Complexes with Pyridylazo Compounds"], "weko_shared_id": 3}
Redox Potentials and HPLC Behavior of Cobalt and Iron Complexes with Pyridylazo Compounds
https://nitech.repo.nii.ac.jp/records/5413
https://nitech.repo.nii.ac.jp/records/5413675c69a5-5859-4152-bf18-08aa2f193d6d
名前 / ファイル | ライセンス | アクション |
---|---|---|
本文_fulltext (711.8 kB)
|
2008 c The Japan Society for Analytical Chemistry
|
Item type | 学術雑誌論文 / Journal Article(1) | |||||
---|---|---|---|---|---|---|
公開日 | 2012-11-06 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Redox Potentials and HPLC Behavior of Cobalt and Iron Complexes with Pyridylazo Compounds | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Yasui, Takashi
× Yasui, Takashi× Nunome, Yoko× Onishi, Takashi× Yamaguchi, Masayo× Tamamura, Saki× Yamada, Hiromichi× Yuchi, Akio |
|||||
著者別名 | ||||||
姓名 | 安井, 孝志 | |||||
著者別名 | ||||||
姓名 | 湯地, 昭夫 | |||||
書誌情報 |
Analytical sciences : the international journal of the Japan Society for Analytical Chemistry 巻 24, 号 12, p. 1575-1580, 発行日 2008-12 |
|||||
出版者 | ||||||
出版者 | The Japan Society for Analytical Chemistry | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 09106340 | |||||
書誌レコードID(NCID) | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA10500785 | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
DOI | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | DOI | |||||
関連識別子 | http://dx.doi.org/10.2116/analsci.24.1575 | |||||
関連名称 | 10.2116/analsci.24.1575 | |||||
内容記述 | ||||||
内容記述タイプ | Other | |||||
内容記述 | The redox potentials of cobalt and iron complexes with ten pyridylazo compounds, E0ML2 (ML2+/0; M: CoIII/II, FeIII/II; L-: pyridylazo compounds), have been determined in order to explore the difference in their reversed-phase HPLC behavior. The redox potentials of Co complexes were in the range of -0.62 - 0.03 V, while those of Fe complexes were -0.06 - 0.59 V relative to 0.20 V for ferricinium/ferrocene. The redox potentials of both the Co and Fe complexes were linearly correlated to the basicities of the ligands. The correlation was quantitatively explained by a difference in dependence of the stabilities of MIII and MII complexes on the ligand basicities. The complex of [CoIIIL2]+ or [FeIIL2] with any compound injected in the reversed-phase HPLC system was detected without any change in the composition. When [CoIIL2] was injected, only those complexes having the highest potentials of E0CoL2 ? 0.0 V were detected as [CoIIL2], while other complexes having lower potentials gave a peak of [CoIIIL2]+. When [FeIIIL2]+ was injected, only complexes having the lowest potentials of E0FeL2 ? 0.0 V were detected as [FeIIIL2]+, while others having higher potentials gave a peak of [FeIIL2]. | |||||
フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf |