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Syntheses and crystal structures of Ge-bearing layered carbides Zr_2Al_4C_5 and Zr_3Al_4C_6
https://nitech.repo.nii.ac.jp/records/5418
https://nitech.repo.nii.ac.jp/records/5418f1a062e3-f39e-4946-b387-547854ebb26f
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
本文_fulltext (813.2 kB)
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(c) 2009 The Ceramic Society of Japan
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||||||||||||||
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| 公開日 | 2012-11-06 | |||||||||||||||||
| タイトル | ||||||||||||||||||
| タイトル | Syntheses and crystal structures of Ge-bearing layered carbides Zr_2Al_4C_5 and Zr_3Al_4C_6 | |||||||||||||||||
| 言語 | en | |||||||||||||||||
| 言語 | ||||||||||||||||||
| 言語 | eng | |||||||||||||||||
| 資源タイプ | ||||||||||||||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||||||||||
| 資源タイプ | journal article | |||||||||||||||||
| 著者 |
Sugiura, Keita
× Sugiura, Keita
× Iwata, Tomoyuki
× Sunada, Naohiro
× Hashimoto, Shinobu
× Nakano, Hiromi
× Fukuda, Koichiro
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| 著者別名 | ||||||||||||||||||
| 姓名 | 橋本, 忍 | |||||||||||||||||
| 著者別名 | ||||||||||||||||||
| 姓名 | 福田, 功一郎 | |||||||||||||||||
| bibliographic_information |
en : Journal of the Ceramic Society of Japan 巻 117, 号 1361, p. 22-26, 発行日 2009-01-01 |
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| 出版者 | ||||||||||||||||||
| 出版者 | The Ceramic Society of Japan | |||||||||||||||||
| 言語 | en | |||||||||||||||||
| ISSN | ||||||||||||||||||
| 収録物識別子タイプ | ISSN | |||||||||||||||||
| 収録物識別子 | 1882-0743 | |||||||||||||||||
| item_10001_source_id_32 | ||||||||||||||||||
| 収録物識別子タイプ | NCID | |||||||||||||||||
| 収録物識別子 | AA12229489 | |||||||||||||||||
| 出版タイプ | ||||||||||||||||||
| 出版タイプ | VoR | |||||||||||||||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||||||||||||||
| item_10001_relation_34 | ||||||||||||||||||
| 関連タイプ | isIdenticalTo | |||||||||||||||||
| 識別子タイプ | DOI | |||||||||||||||||
| 関連識別子 | http://dx.doi.org/10.2109/jcersj2.117.22 | |||||||||||||||||
| 関連名称 | 10.2109/jcersj2.117.22 | |||||||||||||||||
| 内容記述 | ||||||||||||||||||
| 内容記述タイプ | Other | |||||||||||||||||
| 内容記述 | Two types of new quaternary carbide solid solutions, (ZrC)_2Al_3[Al_<1-x>Ge_x]C_3 (x=0.07) and (ZrC)_3Al_3[Al_<1-y>Ge_y]C_3 (y=0.04), have been synthesized and characterized using a laboratory X-ray powder diffractometer (XRPD) and a transmission electron microscope (TEM) equipped with an energy dispersive X-ray analyzer (EDX). With the former carbide, the layered structure was imaged by TEM and the solubility of Ge in the crystal was confirmed by EDX. The crystal structures of both carbides were refined by the Rietveld analysis of the XRPD data. These carbides have been found to form a homologous series with the general formula (ZrC)_mAl_3[Al_<1-z>Ge_z]C_3 (0?z?0.07), where m=2 and 3. The crystal structures can be regarded as intergrowth structures, consisting of the NaCl-type [Zr_mC_<m+1>] slabs separated by the Al_4C_3-type [Al_<4-Z>Ge_zC_4] layers. | |||||||||||||||||
| 言語 | en | |||||||||||||||||
