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Structural study of monosubstituted β-cyclodextrins. crystal structures of phenylthio-β-cyclodextrin and phenylsulphinyl-β- cyclodextrin and spectroscopic study of related compounds in aqueous solution
https://nitech.repo.nii.ac.jp/records/3885
https://nitech.repo.nii.ac.jp/records/38859e82e8f4-2929-4a15-bce9-784123b5718d
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
本文_fulltext (889.9 kB)
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J. CHEM. SOC. PERKIN TRANS. I I 1987 , 7-14 -Reproduced by permission of The Royal Society of Chemistry (RSC)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||||||||||||||||
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| 公開日 | 2012-11-06 | |||||||||||||||||||
| タイトル | ||||||||||||||||||||
| タイトル | Structural study of monosubstituted β-cyclodextrins. crystal structures of phenylthio-β-cyclodextrin and phenylsulphinyl-β- cyclodextrin and spectroscopic study of related compounds in aqueous solution | |||||||||||||||||||
| 言語 | en | |||||||||||||||||||
| 言語 | ||||||||||||||||||||
| 言語 | eng | |||||||||||||||||||
| 資源タイプ | ||||||||||||||||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||||||||||||
| 資源タイプ | journal article | |||||||||||||||||||
| 著者 |
Kamitori, Shigehiro
× Kamitori, Shigehiro
× Hirotsu, Ken
× Higuchi, Taiichi
× Fujita, Kahee
× Yamamura, Hatsuo
× Imoto, Taiji
× Tabushi, Iwao
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| 著者別名 | ||||||||||||||||||||
| 姓名 | 山村, 初雄 | |||||||||||||||||||
| bibliographic_information |
en : Journal of the Chemical Society. Perkin transactions 2 巻 1987, 号 1, p. 7-14, 発行日 1987-01-01 |
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| 出版者 | ||||||||||||||||||||
| 出版者 | Royal Society of Chemistry | |||||||||||||||||||
| 言語 | en | |||||||||||||||||||
| ISSN | ||||||||||||||||||||
| 収録物識別子タイプ | ISSN | |||||||||||||||||||
| 収録物識別子 | 1472-779X | |||||||||||||||||||
| item_10001_source_id_32 | ||||||||||||||||||||
| 収録物識別子タイプ | NCID | |||||||||||||||||||
| 収録物識別子 | AA11413697 | |||||||||||||||||||
| 出版タイプ | ||||||||||||||||||||
| 出版タイプ | VoR | |||||||||||||||||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||||||||||||||||
| item_10001_relation_34 | ||||||||||||||||||||
| 関連タイプ | isIdenticalTo | |||||||||||||||||||
| 識別子タイプ | DOI | |||||||||||||||||||
| 関連識別子 | http://dx.doi.org/10.1039/P29870000007 | |||||||||||||||||||
| 関連名称 | 10.1039/P29870000007 | |||||||||||||||||||
| 内容記述 | ||||||||||||||||||||
| 内容記述タイプ | Other | |||||||||||||||||||
| 内容記述 | The crystal structures of two monosubstituted β-cyclodextrins which have bulky hydrophobic groups instead of primary hydroxy groups were determined by X-ray diffraction. These compounds consist of the host (cyclodextrin moieties) and guest parts (hydrophobic groups), and have the ability to act as both host and guest at the same time. The crystal structures were solved by using Patterson maps, rotation functions, and trial-and-error methods combined with a rigid-body least-squares technique. The structures were refined by using a block-diagonal least-squares method to R values of 0.14 and 0.13. Hydrophobic groups are intermolecularly included in the cyclodextrin cavity of another molecule, and novel helical polymers are formed by repetition of this intermolecular inclusion. A spectroscopic study confirmed that this intermolecular inclusion occurs in aqueous solution. | |||||||||||||||||||
| 言語 | en | |||||||||||||||||||
