{"_buckets": {"deposit": "c0cfd3c1-63da-4933-b43c-e139e6fa9e2f"}, "_deposit": {"created_by": 3, "id": "4121", "owners": [3], "pid": {"revision_id": 0, "type": "depid", "value": "4121"}, "status": "published"}, "_oai": {"id": "oai:nitech.repo.nii.ac.jp:00004121", "sets": ["31"]}, "author_link": ["12174", "12170", "5377", "5128", "8761"], "item_10001_biblio_info_28": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "1992-01-01", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "23", "bibliographicPageEnd": "3459", "bibliographicPageStart": "3451", "bibliographicVolumeNumber": "88", "bibliographic_titles": [{"bibliographic_title": "Journal of the Chemical Society. Faraday transactions."}]}]}, "item_10001_description_36": {"attribute_name": "内容記述", "attribute_value_mlt": [{"subitem_description": "N-Octanoyl-L-glutamic acid oligomers (residue number, N = 3-6, 8, 10, 12, 14, 16, 18, 20 and 22) have been synthesized in order to study their molecular conformations in the solid state. The X-ray diffraction powder patterns and the vibrational spectra of these oligomers have been investigated and compared with those of two β-forms (β1 and β2) and the α-helix of poly(L-glutamic acid). The results are summarized as follows. These oligomers take up a β1- or β2-like structure, similar to that of the two  β-forms of poly(L-glutamic acid). The methods used to precipitate the samples are related to the conformational preferences in the solid state. β1 ? β2 interconversion is possible by reprecipitation of the sample. Preferential stabilization of the β1- or β2-forms is strongly dependent on the residue number. Films of the oligomers, made by casting them from a dimethylformamide solution onto NaCl or KBr plates, take up an α-helical structure, and the α → β1  or α → β2 transition depends on the residue number of the cast film.", "subitem_description_type": "Other"}]}, "item_10001_description_38": {"attribute_name": "フォーマット", "attribute_value_mlt": [{"subitem_description": "application/pdf", "subitem_description_type": "Other"}]}, "item_10001_full_name_27": {"attribute_name": "著者別名", "attribute_value_mlt": [{"nameIdentifiers": [{"nameIdentifier": "8761", "nameIdentifierScheme": "WEKO"}], "names": [{"name": "多賀, 圭次郎"}]}]}, "item_10001_publisher_29": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "Royal Society of Chemistry"}]}, "item_10001_relation_34": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_name": [{"subitem_relation_name_text": "10.1039/FT9928803451"}], "subitem_relation_type": "isIdenticalTo", "subitem_relation_type_id": {"subitem_relation_type_id_text": "http://dx.doi.org/10.1039/FT9928803451", "subitem_relation_type_select": "DOI"}}]}, "item_10001_source_id_30": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "09565000", "subitem_source_identifier_type": "ISSN"}]}, "item_10001_source_id_32": {"attribute_name": "書誌レコードID（NCID）", "attribute_value_mlt": [{"subitem_source_identifier": "AA10743481", "subitem_source_identifier_type": "NCID"}]}, "item_10001_version_type_33": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_970fb48d4fbd8a85", "subitem_version_type": "VoR"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Uehara, Toshiyuki", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "12170", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Okabayashi, Hirofumi", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "5128", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Taga, Keijiro", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "8761", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Yoshida, Tadayoshi", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "5377", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kojima, Hiroshi", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "12174", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2017-01-23"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "JCSF 88_3451.pdf", "filesize": [{"value": "1.2 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensefree": "J. CHEM. SOC. FARADAY TRANS., 1992, 88(23), 3451-3459 -Reproduced by permission of The Royal Society of Chemistry (RSC)", "licensetype": "license_free", "mimetype": "application/pdf", "size": 1200000.0, "url": {"label": "本文_fulltext", "url": "https://nitech.repo.nii.ac.jp/record/4121/files/JCSF 88_3451.pdf"}, "version_id": "899c1f11-d1dc-42c8-b578-774639793945"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Two β-forms and the α-helix of N-octanoyl-L-glutamic acid oligomers", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Two β-forms and the α-helix of N-octanoyl-L-glutamic acid oligomers", "subitem_title_language": "en"}]}, "item_type_id": "10001", "owner": "3", "path": ["31"], "permalink_uri": "https://nitech.repo.nii.ac.jp/records/4121", "pubdate": {"attribute_name": "公開日", "attribute_value": "2012-11-06"}, "publish_date": "2012-11-06", "publish_status": "0", "recid": "4121", "relation": {}, "relation_version_is_last": true, "title": ["Two β-forms and the α-helix of N-octanoyl-L-glutamic acid oligomers"], "weko_shared_id": 3}