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  1. 研究論文

Dissolution of hydrogen and deuterium in titanium, Ti94Al6 and Ti3Al

https://nitech.repo.nii.ac.jp/records/4320
https://nitech.repo.nii.ac.jp/records/4320
58092452-2e4f-413e-a987-c2dbf1489f80
名前 / ファイル ライセンス アクション
JCSF 本文_fulltext (995.1 kB)
J. CHEM. SOC. FARADAY TRANS., 1995, 91(13), 1967-1973 -Reproduced by permission of The Royal Society of Chemistry (RSC)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2012-11-06
タイトル
タイトル Dissolution of hydrogen and deuterium in titanium, Ti94Al6 and Ti3Al
言語 en
言語
言語 eng
資源タイプ
資源タイプ識別子 http://purl.org/coar/resource_type/c_6501
資源タイプ journal article
著者 Naito, Shizuo

× Naito, Shizuo

en Naito, Shizuo

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Yamamoto, Masahiro

× Yamamoto, Masahiro

en Yamamoto, Masahiro

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Doi, Minoru

× Doi, Minoru

en Doi, Minoru

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Kimura, Masao

× Kimura, Masao

en Kimura, Masao

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著者別名
姓名 土井, 稔
bibliographic_information en : Journal of the Chemical Society. Faraday transactions.

巻 91, 号 13, p. 1967-1973, 発行日 1995-01-01
出版者
出版者 Royal Society of Chemistry
言語 en
ISSN
収録物識別子タイプ ISSN
収録物識別子 0956-5000
item_10001_source_id_32
収録物識別子タイプ NCID
収録物識別子 AA10743481
出版タイプ
出版タイプ VoR
出版タイプResource http://purl.org/coar/version/c_970fb48d4fbd8a85
item_10001_relation_34
関連タイプ isIdenticalTo
識別子タイプ DOI
関連識別子 http://dx.doi.org/10.1039/FT9959101967
関連名称 10.1039/FT9959101967
内容記述
内容記述タイプ Other
内容記述 The solubility of hydrogen and deuterium in α-, α,β- and β-titanium, Ti94Al6 and in α2-Ti3Al has been volumetrically measured in the ranges of temperature 623-1323 K and hydrogen concentration (atomic ratio) 0.001-0.25. The equilibrium hydrogen pressure at a given temperature and hydrogen concentration has been found to increase greatly as the aluminium content increases. This is explicable on the assumption that aluminium atoms block some of the sites available to hydrogen atoms. In contrast, the heat of solution of hydrogen only slightly increases with the aluminium content and in α-titanium, α-Ti94Al6 and α2-Ti3Al, the ratio of the deuterium pressure to the hydrogen pressure at identical hydrogen and deuterium concentrations is almost independent of the aluminium content. A possible cause of the small dependence of the measured heat and ratio on the aluminium content is discussed and occupation of the tetrahedral site by hydrogen atoms is suggested for α-titanium, α-T94Al6 and α2-Ti3Al. The origin of the sloping plateaus observed in the pressure-composition isotherms for α, β-Ti94Al6 is also briefly discussed.
言語 en
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