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  1. 研究論文

Vibrational spectra of N-acetylglycine oligomers. Part 2. - Raman scattering study of selectively C-deuteriated oligomers with polyglycine I- and II-type structures

https://nitech.repo.nii.ac.jp/records/4461
https://nitech.repo.nii.ac.jp/records/4461
c01d5c0f-2887-4be1-aba9-6e5e1b0a314b
名前 / ファイル ライセンス アクション
JCSF 本文_fulltext (511.1 kB)
J. Chem. Soc., Faraday T rans., 1997, 93(2), 313-319 -Reproduced by permission of The Royal Society of Chemistry (RSC)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2012-11-06
タイトル
言語 en
タイトル Vibrational spectra of N-acetylglycine oligomers. Part 2. - Raman scattering study of selectively C-deuteriated oligomers with polyglycine I- and II-type structures
言語
言語 eng
資源タイプ
資源タイプ識別子 http://purl.org/coar/resource_type/c_6501
資源タイプ journal article
著者 Etori, Hideki

× Etori, Hideki

WEKO 11688

en Etori, Hideki

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Taga, Keijiro

× Taga, Keijiro

WEKO 8761

en Taga, Keijiro

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Okabayashi, Hirofumi

× Okabayashi, Hirofumi

WEKO 5128

en Okabayashi, Hirofumi

Search repository
Oshima, Kunihiro

× Oshima, Kunihiro

WEKO 13755

en Oshima, Kunihiro

Search repository
著者別名
姓名 多賀, 圭次郎
書誌情報 Journal of the Chemical Society. Faraday transactions.

巻 93, 号 12, p. 313-319, 発行日 1997-01-01
出版者
出版者 Royal Society of Chemistry
ISSN
収録物識別子タイプ ISSN
収録物識別子 09565000
書誌レコードID(NCID)
収録物識別子タイプ NCID
収録物識別子 AA10743481
著者版フラグ
出版タイプ VoR
出版タイプResource http://purl.org/coar/version/c_970fb48d4fbd8a85
DOI
関連タイプ isIdenticalTo
識別子タイプ DOI
関連識別子 http://dx.doi.org/10.1039/A605741A
関連名称 10.1039/A605741A
内容記述
内容記述タイプ Other
内容記述 Selectively C-deuteriated N-acetylglycine trimer and tetramer acid types have been synthesized, and their two crystalline modifications, solid-A and solid-B [which correspond in structure to polyglycine (PG) II and I, respectively] have been prepared. Raman scattering spectra have been measured for a series of these glycine oligomers, and the CH2- and CD2-characteristic modes have been investigated in detail. Assignment of the CH2-characteristic bands to each CH2 group in the oligomers has been carried out successfully. In particular, the results obtained from the CD2 stretch region show that N- and C-terminal glycine residues for the PGI- and PGII-type trimers and tetramers are all in very similar environments and that the glycine residues which are sandwiched between the two terminal residues are also in a similar environment for both the trimers and the tetramers.
フォーマット
内容記述タイプ Other
内容記述 application/pdf
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