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Utility of 1-Octanol/Octane Mixed Solvents for the Solvent Extraction of Aluminum(III), Gallium(III), and Indium(III) with 8-Quinolinol
https://nitech.repo.nii.ac.jp/records/5292
https://nitech.repo.nii.ac.jp/records/5292a7537bed-8b9c-4b64-ad44-3d564660c5bd
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
本文_fulltext (126.9 kB)
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2006 c The Japan Society for Analytical Chemistry
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 公開日 | 2012-11-06 | |||||||||||
| タイトル | ||||||||||||
| タイトル | Utility of 1-Octanol/Octane Mixed Solvents for the Solvent Extraction of Aluminum(III), Gallium(III), and Indium(III) with 8-Quinolinol | |||||||||||
| 言語 | en | |||||||||||
| 言語 | ||||||||||||
| 言語 | eng | |||||||||||
| 資源タイプ | ||||||||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||||
| 資源タイプ | journal article | |||||||||||
| 著者 |
Yamada, Hiromichi
× Yamada, Hiromichi
× Hayashi, Hiroyuki
× Yasui, Takashi
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| 著者別名 | ||||||||||||
| 姓名 | 安井, 孝志 | |||||||||||
| 書誌情報 |
en : Analytical sciences : the international journal of the Japan Society for Analytical Chemistry 巻 22, 号 3, p. 371-376, 発行日 2006-05 |
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| 出版者 | ||||||||||||
| 出版者 | The Japan Society for Analytical Chemistry | |||||||||||
| 言語 | en | |||||||||||
| ISSN | ||||||||||||
| 収録物識別子タイプ | ISSN | |||||||||||
| 収録物識別子 | 0910-6340 | |||||||||||
| item_10001_source_id_32 | ||||||||||||
| 収録物識別子タイプ | NCID | |||||||||||
| 収録物識別子 | AA10500785 | |||||||||||
| 出版タイプ | ||||||||||||
| 出版タイプ | VoR | |||||||||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||||||||
| item_10001_relation_34 | ||||||||||||
| 関連タイプ | isIdenticalTo | |||||||||||
| 識別子タイプ | DOI | |||||||||||
| 関連識別子 | http://dx.doi.org/10.2116/analsci.22.371 | |||||||||||
| 関連名称 | 10.2116/analsci.22.371 | |||||||||||
| 内容記述 | ||||||||||||
| 内容記述タイプ | Other | |||||||||||
| 内容記述 | Using 1-octanol/octane mixed solvents, the extraction of aluminum(III), gallium(III) and indium(III) with 8-quinolinol was carried out at 25°C. The formation constants of the respective metal(III) 8-quinolinolates in the aqueous phase and their partition constants between the mixed solvents and water were determined based on an analysis of the extraction equilibria. The relationship between the partition constants of 8-quinolinol and its complexes was analyzed by the regular solution theory. The molar volumes of aluminum(III), gallium(III) and indium(III) 8-quinolinolates, calculated from the present results, suggest that the electrostriction effect functions in complex forming. It has been found that octane/1-octanol mixed solvents were available not only for the extraction of metal ions, but also for determining the formation constants of these metal 8-quinolinolates in the aqueous phase and their partition constants. | |||||||||||
| 言語 | en | |||||||||||
