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  1. 研究論文

Features in optical absorption and photocurrent spectra of organic solar cells due to organic/organic interface

https://nitech.repo.nii.ac.jp/records/5529
https://nitech.repo.nii.ac.jp/records/5529
d0bcf89d-d6b2-487c-9bc8-382735ed60b1
名前 / ファイル ライセンス アクション
SogaTetsuo_2011_AIP.pdf 本文_fulltext (2.4 MB)
Copyright (2011) American Institute of Physics. This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Institute of Physics.The following article appeared in Journal of Applied Physics, 109, 103109 ; 2011 and may be found at http://dx.doi.org/10.1063/1.3586520
Item type 学術雑誌論文 / Journal Article(1)
公開日 2013-04-01
タイトル
タイトル Features in optical absorption and photocurrent spectra of organic solar cells due to organic/organic interface
言語 en
言語
言語 eng
資源タイプ
資源タイプ識別子 http://purl.org/coar/resource_type/c_6501
資源タイプ journal article
著者 Ismail, Y. A M

× Ismail, Y. A M

en Ismail, Y. A M

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曾我, 哲夫

× 曾我, 哲夫

en Soga, Tetsuo

ja 曾我, 哲夫
ISNI

ja-Kana ソガ, テツオ


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Jimbo, Takashi

× Jimbo, Takashi

en Jimbo, Takashi

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著者別名
姓名 Soga, Tetsuo
言語 en
姓名 曾我, 哲夫
言語 ja
姓名 ソガ, テツオ
言語 ja-Kana
書誌情報 en : Journal of Applied Physics

巻 109, 号 10, p. 103109-1-103109-7, 発行日 2011-05-15
出版者
出版者 American Institute of Physics
言語 en
ISSN
収録物識別子タイプ ISSN
収録物識別子 0021-8979
item_10001_source_id_32
収録物識別子タイプ NCID
収録物識別子 AA00693547
出版タイプ
出版タイプ VoR
出版タイプResource http://purl.org/coar/version/c_970fb48d4fbd8a85
item_10001_relation_34
関連タイプ isIdenticalTo
識別子タイプ DOI
関連識別子 http://dx.doi.org/10.1063/1.3586520
関連名称 10.1063/1.3586520
内容記述
内容記述タイプ Other
内容記述 We surprisingly found that, organic/organic interface had a direct and pronounced impact on optical absorption and photocurrent spectra of organic solar cell at a favorable wavelength region of the visible solar spectrum. The organic/organic interface was formed as a result of connection between coumarin 6 (C6): [6,6]-phenyl-C 61 butyric acid methyl ester (PCBM) blend films and indium-tin oxide (ITO)/poly(3,4-ethylenedioxythiophene) doped with poly(styrene sulfonate) (PEDOT:PSS) electrode. Optical absorption measurement was carried out for ITO/PEDOT:PSS/C6:PCBM films, while external quantum efficiency measurement was carried out for ITO/PEDOT:PSS/C6:PCBM/Al solar cells, with varying C6:PCBM blend concentration. We found that, the C6:PCBM blend in the ITO/PEDOT:PSS/C6:PCBM films had an additional feature in the absorption spectra at the wavelength range of 520-800 nm, at which the C6 dye, PCBM, PEDOT:PSS, and ITO were transparent. An additional feature, also, appeared in photocurrent spectra of the C6:PCBM films in the ITO/PEDOT:PSS/C6:PCBM/Al solar cells at the same wavelength range. The new features in the optical absorption and photocurrent spectra of the investigated solar cells originated, in all probability, due to optically induced sup-band transitions in the C6:PCBM blend films at the interface with ITO/PEDOT:PSS electrode. Thus, the C6:PCBM blend films produced a charge carrier generation interface due to connection with ITO/PEDOT:PSS electrode. As a result of this charge carrier generation interface, the power conversion efficiency of the corresponding solar cell is improved. Taking into consideration these new findings, the high-band-gap organic materials will take more importance as sensitizers in organic optoelectronic applications.
言語 en
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