WEKO3
アイテム
{"_buckets": {"deposit": "51f5436d-d06b-42db-9302-2e85ac69ad3b"}, "_deposit": {"created_by": 3, "id": "4865", "owners": [3], "pid": {"revision_id": 0, "type": "depid", "value": "4865"}, "status": "published"}, "_oai": {"id": "oai:nitech.repo.nii.ac.jp:00004865", "sets": ["31"]}, "author_link": ["15857", "15856", "10237", "8739"], "item_10001_biblio_info_28": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2000-09-06", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "18", "bibliographicPageEnd": "3148", "bibliographicPageStart": "3143", "bibliographicVolumeNumber": "2000", "bibliographic_titles": [{"bibliographic_title": "Journal of the Chemical Society. Perkin transactions 1"}]}]}, "item_10001_description_36": {"attribute_name": "内容記述", "attribute_value_mlt": [{"subitem_description": "Reduction of γ-keto sulfoxides bearing the 2,4,6-triisopropylphenyl group with DIBAL gives γ-hydroxy sulfoxides with high stereoselectivity in the ratio 95:5. In comparison with the lower stereoselectivities obtained in the reaction of γ-keto sulfoxides bearing p-tolyl or 2,4,6-trimethylphenyl groups, the sterically bulky (2,4,6-triisopropylphenyl)-sulfinyl group is extremely efficient in effecting high 1,4-remote asymmetric induction.", "subitem_description_type": "Other"}]}, "item_10001_description_38": {"attribute_name": "フォーマット", "attribute_value_mlt": [{"subitem_description": "application/pdf", "subitem_description_type": "Other"}]}, "item_10001_full_name_27": {"attribute_name": "著者別名", "attribute_value_mlt": [{"nameIdentifiers": [{"nameIdentifier": "8739", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "1000020335087", "nameIdentifierScheme": "NRID", "nameIdentifierURI": "http://rns.nii.ac.jp/nr/1000020335087"}], "names": [{"name": "中村, 修一"}]}, {"nameIdentifiers": [{"nameIdentifier": "10237", "nameIdentifierScheme": "WEKO"}], "names": [{"name": "融, 健"}]}]}, "item_10001_publisher_29": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "Royal Society of Chemistry"}]}, "item_10001_relation_34": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_name": [{"subitem_relation_name_text": "10.1039/b004782l"}], "subitem_relation_type": "isIdenticalTo", "subitem_relation_type_id": {"subitem_relation_type_id_text": "http://dx.doi.org/10.1039/b004782l", "subitem_relation_type_select": "DOI"}}]}, "item_10001_source_id_30": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "14727781", "subitem_source_identifier_type": "ISSN"}]}, "item_10001_source_id_32": {"attribute_name": "書誌レコードID(NCID)", "attribute_value_mlt": [{"subitem_source_identifier": "AA11413675", "subitem_source_identifier_type": "NCID"}]}, "item_10001_version_type_33": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_970fb48d4fbd8a85", "subitem_version_type": "VoR"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Nakamura, Shuichi", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "8739", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "1000020335087", "nameIdentifierScheme": "NRID", "nameIdentifierURI": "http://rns.nii.ac.jp/nr/1000020335087"}]}, {"creatorNames": [{"creatorName": "Kuroyanagi, Masayuki", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "15856", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Watanabe, Yoshihiko", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "15857", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Toru, Takeshi", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "10237", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2017-01-24"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "JCSP 2000_3143.pdf", "filesize": [{"value": "195.7 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensefree": "J. Chem. Soc., Perkin Trans. 1, 2000, 3143-3148 -Reproduced by permission of The Royal Society of Chemistry (RSC)", "licensetype": "license_free", "mimetype": "application/pdf", "size": 195700.0, "url": {"label": "本文_fulltext", "url": "https://nitech.repo.nii.ac.jp/record/4865/files/JCSP 2000_3143.pdf"}, "version_id": "653ee4b6-16f0-43b1-8bb7-79b8a5b79366"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "1,4-Asymmetric reduction of γ-keto sulfoxides bearing the 2,4,6-triisopropylphenyl group", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "1,4-Asymmetric reduction of γ-keto sulfoxides bearing the 2,4,6-triisopropylphenyl group", "subitem_title_language": "en"}]}, "item_type_id": "10001", "owner": "3", "path": ["31"], "permalink_uri": "https://nitech.repo.nii.ac.jp/records/4865", "pubdate": {"attribute_name": "公開日", "attribute_value": "2012-11-06"}, "publish_date": "2012-11-06", "publish_status": "0", "recid": "4865", "relation": {}, "relation_version_is_last": true, "title": ["1,4-Asymmetric reduction of γ-keto sulfoxides bearing the 2,4,6-triisopropylphenyl group"], "weko_shared_id": 3}
1,4-Asymmetric reduction of γ-keto sulfoxides bearing the 2,4,6-triisopropylphenyl group
https://nitech.repo.nii.ac.jp/records/4865
https://nitech.repo.nii.ac.jp/records/4865e1383544-e3a0-4875-9a8c-c592facf1063
名前 / ファイル | ライセンス | アクション |
---|---|---|
本文_fulltext (195.7 kB)
|
J. Chem. Soc., Perkin Trans. 1, 2000, 3143-3148 -Reproduced by permission of The Royal Society of Chemistry (RSC)
|
Item type | 学術雑誌論文 / Journal Article(1) | |||||
---|---|---|---|---|---|---|
公開日 | 2012-11-06 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | 1,4-Asymmetric reduction of γ-keto sulfoxides bearing the 2,4,6-triisopropylphenyl group | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Nakamura, Shuichi
× Nakamura, Shuichi× Kuroyanagi, Masayuki× Watanabe, Yoshihiko× Toru, Takeshi |
|||||
著者別名 | ||||||
姓名 | 中村, 修一 | |||||
著者別名 | ||||||
姓名 | 融, 健 | |||||
書誌情報 |
Journal of the Chemical Society. Perkin transactions 1 巻 2000, 号 18, p. 3143-3148, 発行日 2000-09-06 |
|||||
出版者 | ||||||
出版者 | Royal Society of Chemistry | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 14727781 | |||||
書誌レコードID(NCID) | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA11413675 | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
DOI | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | DOI | |||||
関連識別子 | http://dx.doi.org/10.1039/b004782l | |||||
関連名称 | 10.1039/b004782l | |||||
内容記述 | ||||||
内容記述タイプ | Other | |||||
内容記述 | Reduction of γ-keto sulfoxides bearing the 2,4,6-triisopropylphenyl group with DIBAL gives γ-hydroxy sulfoxides with high stereoselectivity in the ratio 95:5. In comparison with the lower stereoselectivities obtained in the reaction of γ-keto sulfoxides bearing p-tolyl or 2,4,6-trimethylphenyl groups, the sterically bulky (2,4,6-triisopropylphenyl)-sulfinyl group is extremely efficient in effecting high 1,4-remote asymmetric induction. | |||||
フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf |