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Crystal Structures of Trifluoromethanesulfonato Complexes of Nickel(II) and Palladium(II), [Ni(bpy)2(CF3SO3)2] and [Pd(triphosphine)(CF3SO3)](CF3SO3)・C6H6, and Characterization of the Coordination Ability of CF3SO3-
https://nitech.repo.nii.ac.jp/records/4362
https://nitech.repo.nii.ac.jp/records/436231009f0a-b84b-4f66-8494-7a1205a4fdaa
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
本文_fulltext (400.6 kB)
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1995 c The Japan Society for Analytical Chemistry
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||||||||||
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| 公開日 | 2012-11-06 | |||||||||||||
| タイトル | ||||||||||||||
| タイトル | Crystal Structures of Trifluoromethanesulfonato Complexes of Nickel(II) and Palladium(II), [Ni(bpy)2(CF3SO3)2] and [Pd(triphosphine)(CF3SO3)](CF3SO3)・C6H6, and Characterization of the Coordination Ability of CF3SO3- | |||||||||||||
| 言語 | en | |||||||||||||
| 言語 | ||||||||||||||
| 言語 | eng | |||||||||||||
| 資源タイプ | ||||||||||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||||||
| 資源タイプ | journal article | |||||||||||||
| 著者 |
Aizawa, Shinichi
× Aizawa, Shinichi
× Yagyu, Takeyoshi
× Kato, Kaoru
× Funahashi, Shigenobu
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| 著者別名 | ||||||||||||||
| 姓名 | 柳生, 剛義 | |||||||||||||
| 書誌情報 |
en : Analytical sciences : the international journal of the Japan Society for Analytical Chemistry 巻 11, 号 4, p. 557-562, 発行日 1995-08 |
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| 出版者 | ||||||||||||||
| 出版者 | The Japan Society for Analytical Chemistry | |||||||||||||
| 言語 | en | |||||||||||||
| ISSN | ||||||||||||||
| 収録物識別子タイプ | ISSN | |||||||||||||
| 収録物識別子 | 0910-6340 | |||||||||||||
| item_10001_source_id_32 | ||||||||||||||
| 収録物識別子タイプ | NCID | |||||||||||||
| 収録物識別子 | AA10500785 | |||||||||||||
| 出版タイプ | ||||||||||||||
| 出版タイプ | VoR | |||||||||||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||||||||||
| item_10001_relation_34 | ||||||||||||||
| 関連タイプ | isIdenticalTo | |||||||||||||
| 識別子タイプ | DOI | |||||||||||||
| 関連識別子 | http://dx.doi.org/10.2116/analsci.11.557 | |||||||||||||
| 関連名称 | 10.2116/analsci.11.557 | |||||||||||||
| 内容記述 | ||||||||||||||
| 内容記述タイプ | Other | |||||||||||||
| 内容記述 | The bis(trifluoromethanesulfonato)nickel(II) complex with two 2, 2′-bipyridine (bpy), [Ni(bpy)2(CF3SO3)2] (1), and the mono(trifluoromethanesulfonato)palladium(II) complex with bis(2-diphenylphosphinoethyl)phenylphosphine (p3), [Pd(p3)(CF3SO3)](CF3SO3)・C6H6 (2), were isolated. The crystal structures for 1 and 2 have been determined by an X-ray crystal structure analysis. Complex 1 crystallizes in monoclinic space group Aa with a=18.55(1), b=14.48(1), c=9.941(7)A, β=101.98(3)°, and Z=4. Complex 2 crystallizes in the monoclinic space group P21/n with a=17.211(5), b=27.175(7), c=9.962(2)A, β=105.66(2)°, and Z=4. The crystal of 1 contains a distorted octahedral nickel(II) complex with a cis arrangement, and the crystal of 2 contains a distorted square-planar palladium(II) complex. The metal-oxygen bond distances for triflate (CF3SO3-), (2.135(5) and 2.148(4)A for 1 and 2.126(7)A for 2), are comparable to those for the other oxygen donors. Three S-O bond distances in the coordinated triflate are close to one another. The stability of the metal-oxygen bond is discussed in terms of the electronic property of triflate. | |||||||||||||
| 言語 | en | |||||||||||||
