{"_buckets": {"deposit": "44e27d0b-97e7-4041-bbf1-134db832f079"}, "_deposit": {"created_by": 3, "id": "4459", "owners": [3], "pid": {"revision_id": 0, "type": "depid", "value": "4459"}, "status": "published"}, "_oai": {"id": "oai:nitech.repo.nii.ac.jp:00004459", "sets": ["31"]}, "author_link": ["8802", "13744", "13742", "5128", "11688"], "item_10001_biblio_info_28": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "1997-01-01", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "1", "bibliographicPageEnd": "146", "bibliographicPageStart": "143", "bibliographicVolumeNumber": "93", "bibliographic_titles": [{"bibliographic_title": "Journal of the Chemical Society. Faraday transactions."}]}]}, "item_10001_description_36": {"attribute_name": "内容記述", "attribute_value_mlt": [{"subitem_description": "N-Acetylglycine oligomer ethyl esters (residue number, n=3-9) and selectively C-deuteriated oligomer acid types (n=3, 4) have been synthesized. Two crystalline modifications, the A- and B-series [which correspond to polyglycine (PG) II and I in structure, respectively] have been prepared. For the two series of oligomers, the intermolecular hydrogen-bond distance (RN・・・O) and segmental mobility were evaluated using 13C CP MAS and 2H NMR spectra. The results showed that the RN・・・O values for the A- and B-series of oligomer ethyl esters closely correspond to those of PGII and PGI, respectively, and that for the two series of C-deuteriated oligomers segmental mobilities of the CH2 groups of both the N- and C-terminal residues are more restricted than those of the methylenes sandwiched between the terminal residues.", "subitem_description_type": "Other"}]}, "item_10001_description_38": {"attribute_name": "フォーマット", "attribute_value_mlt": [{"subitem_description": "application/pdf", "subitem_description_type": "Other"}]}, "item_10001_full_name_27": {"attribute_name": "著者別名", "attribute_value_mlt": [{"nameIdentifiers": [{"nameIdentifier": "8802", "nameIdentifierScheme": "WEKO"}], "names": [{"name": "吉野, 明広"}]}]}, "item_10001_publisher_29": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "Royal Society of Chemistry"}]}, "item_10001_relation_34": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_name": [{"subitem_relation_name_text": "10.1039/A605775F"}], "subitem_relation_type": "isIdenticalTo", "subitem_relation_type_id": {"subitem_relation_type_id_text": "http://dx.doi.org/10.1039/A605775F", "subitem_relation_type_select": "DOI"}}]}, "item_10001_source_id_30": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "09565000", "subitem_source_identifier_type": "ISSN"}]}, "item_10001_source_id_32": {"attribute_name": "書誌レコードID（NCID）", "attribute_value_mlt": [{"subitem_source_identifier": "AA10743481", "subitem_source_identifier_type": "NCID"}]}, "item_10001_version_type_33": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_970fb48d4fbd8a85", "subitem_version_type": "VoR"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Etori, Hideki", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "11688", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Yoshino, Akihiro", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "8802", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Watanabe, Kazuya", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "13742", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Okabayashi, Hirofumi", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "5128", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Oshima, Kunihiro", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "13744", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2017-01-23"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "JCSF 93_143.pdf", "filesize": [{"value": "290.5 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensefree": "J. Chem. Soc., Faraday T rans., 1997, 93(1), 143-146 - Reproduced by permission of The Royal Society of Chemistry (RSC)", "licensetype": "license_free", "mimetype": "application/pdf", "size": 290500.0, "url": {"label": "本文_fulltext", "url": "https://nitech.repo.nii.ac.jp/record/4459/files/JCSF 93_143.pdf"}, "version_id": "2027b3a9-e15b-4fc5-8e1c-188441dda844"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "13C and 2H NMR  studies of N-acetylglycine oligomer ethyl esters (residue number, n = 3-9) and selectively C-deuteriated oligomer acid types (n = 3, 4): Intermolecular hydrogen-bonding distance and segmental mobility", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "13C and 2H NMR  studies of N-acetylglycine oligomer ethyl esters (residue number, n = 3-9) and selectively C-deuteriated oligomer acid types (n = 3, 4): Intermolecular hydrogen-bonding distance and segmental mobility", "subitem_title_language": "en"}]}, "item_type_id": "10001", "owner": "3", "path": ["31"], "permalink_uri": "https://nitech.repo.nii.ac.jp/records/4459", "pubdate": {"attribute_name": "公開日", "attribute_value": "2012-11-06"}, "publish_date": "2012-11-06", "publish_status": "0", "recid": "4459", "relation": {}, "relation_version_is_last": true, "title": ["13C and 2H NMR  studies of N-acetylglycine oligomer ethyl esters (residue number, n = 3-9) and selectively C-deuteriated oligomer acid types (n = 3, 4): Intermolecular hydrogen-bonding distance and segmental mobility"], "weko_shared_id": 3}