WEKO3
アイテム
{"_buckets": {"deposit": "10b0522d-d67f-4d50-adbd-35be4773786e"}, "_deposit": {"created_by": 3, "id": "3815", "owners": [3], "pid": {"revision_id": 0, "type": "depid", "value": "3815"}, "status": "published"}, "_oai": {"id": "oai:nitech.repo.nii.ac.jp:00003815", "sets": ["31"]}, "author_link": ["9542", "9541", "8811"], "item_10001_biblio_info_28": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "1985-04", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "1", "bibliographicPageEnd": "22", "bibliographicPageStart": "19", "bibliographicVolumeNumber": "1", "bibliographic_titles": [{"bibliographic_title": "Analytical sciences : the international journal of the Japan Society for Analytical Chemistry"}]}]}, "item_10001_description_36": {"attribute_name": "内容記述", "attribute_value_mlt": [{"subitem_description": "The potential response of copper(II), lead and cadmium ion-selective electrodes was studied in ligand buffers which contain a complex ML(M:Cu2+, Pb2+ or Cd2+), a ligand L and an excess of a second metal N. By measuring [M] with the ion-selective electrode, the ratio of the stability constants, KML/KNL was determined. The effects of pH, the second metal ion N and the ratio of [N]/[NL] on the electrode response were studied in detail. The KML/KNL values obtained for EDTA were in good agreement with those calculated from KML and KNL in the literature. The stability constants of N-hydroxyethylenediamine-N, N′, N′-triacetate complexes were determined successfully. These logarithmic values of KNL were found: Pb2+, 15.59; Zn2+, 14.59; Co2+, 14.49; Cd2+, 14.24; Mn2+, 11.41. These results show that the method is very useful for the determination of the stability constants of complexes with metal ions for which suitable ion-selective electrodes are not available.", "subitem_description_type": "Other"}]}, "item_10001_description_38": {"attribute_name": "フォーマット", "attribute_value_mlt": [{"subitem_description": "application/pdf", "subitem_description_type": "Other"}]}, "item_10001_full_name_27": {"attribute_name": "著者別名", "attribute_value_mlt": [{"nameIdentifiers": [{"nameIdentifier": "8811", "nameIdentifierScheme": "WEKO"}], "names": [{"name": "湯地, 昭夫"}]}]}, "item_10001_publisher_29": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "The Japan Society for Analytical Chemistry"}]}, "item_10001_relation_34": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_name": [{"subitem_relation_name_text": "10.2116/analsci.1.19"}], "subitem_relation_type": "isIdenticalTo", "subitem_relation_type_id": {"subitem_relation_type_id_text": "http://dx.doi.org/10.2116/analsci.1.19", "subitem_relation_type_select": "DOI"}}]}, "item_10001_source_id_30": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "09106340", "subitem_source_identifier_type": "ISSN"}]}, "item_10001_source_id_32": {"attribute_name": "書誌レコードID(NCID)", "attribute_value_mlt": [{"subitem_source_identifier": "AA10500785", "subitem_source_identifier_type": "NCID"}]}, "item_10001_version_type_33": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_970fb48d4fbd8a85", "subitem_version_type": "VoR"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Yuchi, Akio", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "8811", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Wada, Hiroko", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "9541", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Nakagawa, Genkichi", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "9542", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2017-01-23"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "AS 1_19.pdf", "filesize": [{"value": "221.3 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensefree": "1985 c The Japan Society for Analytical Chemistry", "licensetype": "license_free", "mimetype": "application/pdf", "size": 221300.0, "url": {"label": "本文_fulltext", "url": "https://nitech.repo.nii.ac.jp/record/3815/files/AS 1_19.pdf"}, "version_id": "0637eab6-6930-4a0c-b273-045e948ec7f9"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Use of Ligand Buffers in the Determination of the Stability Constants of Metal Complexes with Ion-Selective Electrodes", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Use of Ligand Buffers in the Determination of the Stability Constants of Metal Complexes with Ion-Selective Electrodes", "subitem_title_language": "en"}]}, "item_type_id": "10001", "owner": "3", "path": ["31"], "permalink_uri": "https://nitech.repo.nii.ac.jp/records/3815", "pubdate": {"attribute_name": "公開日", "attribute_value": "2012-11-06"}, "publish_date": "2012-11-06", "publish_status": "0", "recid": "3815", "relation": {}, "relation_version_is_last": true, "title": ["Use of Ligand Buffers in the Determination of the Stability Constants of Metal Complexes with Ion-Selective Electrodes"], "weko_shared_id": -1}
Use of Ligand Buffers in the Determination of the Stability Constants of Metal Complexes with Ion-Selective Electrodes
https://nitech.repo.nii.ac.jp/records/3815
https://nitech.repo.nii.ac.jp/records/3815d1a156d9-1f7d-4730-afeb-bbd7df94d0b3
名前 / ファイル | ライセンス | アクション |
---|---|---|
本文_fulltext (221.3 kB)
|
1985 c The Japan Society for Analytical Chemistry
|
Item type | 学術雑誌論文 / Journal Article(1) | |||||
---|---|---|---|---|---|---|
公開日 | 2012-11-06 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Use of Ligand Buffers in the Determination of the Stability Constants of Metal Complexes with Ion-Selective Electrodes | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Yuchi, Akio
× Yuchi, Akio× Wada, Hiroko× Nakagawa, Genkichi |
|||||
著者別名 | ||||||
姓名 | 湯地, 昭夫 | |||||
書誌情報 |
Analytical sciences : the international journal of the Japan Society for Analytical Chemistry 巻 1, 号 1, p. 19-22, 発行日 1985-04 |
|||||
出版者 | ||||||
出版者 | The Japan Society for Analytical Chemistry | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 09106340 | |||||
書誌レコードID(NCID) | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA10500785 | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
DOI | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | DOI | |||||
関連識別子 | http://dx.doi.org/10.2116/analsci.1.19 | |||||
関連名称 | 10.2116/analsci.1.19 | |||||
内容記述 | ||||||
内容記述タイプ | Other | |||||
内容記述 | The potential response of copper(II), lead and cadmium ion-selective electrodes was studied in ligand buffers which contain a complex ML(M:Cu2+, Pb2+ or Cd2+), a ligand L and an excess of a second metal N. By measuring [M] with the ion-selective electrode, the ratio of the stability constants, KML/KNL was determined. The effects of pH, the second metal ion N and the ratio of [N]/[NL] on the electrode response were studied in detail. The KML/KNL values obtained for EDTA were in good agreement with those calculated from KML and KNL in the literature. The stability constants of N-hydroxyethylenediamine-N, N′, N′-triacetate complexes were determined successfully. These logarithmic values of KNL were found: Pb2+, 15.59; Zn2+, 14.59; Co2+, 14.49; Cd2+, 14.24; Mn2+, 11.41. These results show that the method is very useful for the determination of the stability constants of complexes with metal ions for which suitable ion-selective electrodes are not available. | |||||
フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf |